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Chemistry LibreTexts

Continuous Distributions (Worksheet)

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Work in groups on these problems. You should try to answer the questions without referring to your textbook. If you get stuck, try asking another group for help.

A continuous probability distribution represents the histogram of sampling a random variable x that can take on any value (i.e., is continuous). There are many different characteristics used to describe a distribution D(x). Each of the characteristics below commonly show up in discussions of quantum mechanics.

  • The integrated value (A): This is the sum over the distribution over all possible values of x. Graphically, this is the area under the distribution. A=D(x)dx
    If the range of x is less than to (e.g., from a to b), then A is given by A=baD(x)dx
  • The expectation value (x): This is a different term that is used synonymously with the average (or mean) of x over the distribution. The mean is given by ˉx=x=baxD(x)dx
    Notice the difference between Equations ??? and ???.
  • The most probable value (xmp): This is the value of x at the peak of D(x). This is determined from basic calculus for determining extrema and via identifying when the derivative of the distribution is zero. (dD(x)dx)xmp=0
  • The standard deviation (σx): This is the a measure of the spread of the distribution and is given by σ2x=ba(xˉx)2D(x)dx

Applications

One example distribution is the Sine-squared distribution:

D(x)=Nosin2(N1x)

where No and n1 are constants. The range of x goes from 0 to π.

Another is the Gaussian distribution:

D(x)=NoEN1x2

where No and N1 are constants. The range of x goes from to .

Q1

Plot the Sine-squared and Gaussian distributions.

Q2

Calculate the four characteristics defined above for the Gaussian distribution.

Interpretation of a Probability Distribution

A probability distribution is defined such that the likelihood of a value of x being sampled between a and b is equal to the integral (area under the curve) between a and b, e.g., Equation ???. This integrated values is always positive and if the full range of possible x values are integrated over, then the area under the curve from negative infinity to positive infinity is one.

A=baD(x)dx=1

For continuous probability distributions, we cannot calculate exact probability for a specific outcome, but instead we calculate a probability for a range of outcomes (e.g., the probability that a sampled value of x is greater than 10). The probability that a continuous variable will take a specific value is equal to zero. Because of this, we can never express continuous probability distribution in a tabular form. Another way to say this is that the probability for x to take any single value a (that is axa) is zero, because an integral with the same upper and lower limits is always equal to zero.

A=aaD(x)dx=0

Q3

What is the expression for finding x exactly at 0 for a Gaussian probability distribution?

Q4

What is the expression for finding x between one standard deviation on each side of 0 for a Gaussian probability distribution?

Q5

Use the information above to identify the constants No and N1 in the Gaussian Distribution? These integrals may be needed:

ea(x+b)2dx=πa.

ex2dx=20ex2dx

Q6

What is the expression for finding x between 0 and + for a Gaussian probability distribution when No and N1 are determined?

Q7

The Gaussian distribution is called a Normal distribution (sometimes called a bell curve) if its standard deviation is 1 and the area under the distribution is 1 from to +. What is the mathematical formula of the Normal distribution.

Q8

A function converges if it approach a limit more and more closely as an argument (variable) of the function increases or decreases (i.e., Horizontal Asymptotes). For example, the function y=1x converges to zero as x increases. Gaussian functions converge to zero with respect to the argument approaching and +. Explain why this is a required property of a probability distribution.


This page titled Continuous Distributions (Worksheet) is shared under a CC BY-NC-SA 4.0 license and was authored, remixed, and/or curated by Nancy Levinger.

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