Skip to main content
Library homepage
 

Text Color

Text Size

 

Margin Size

 

Font Type

Enable Dyslexic Font
Chemistry LibreTexts

Angular Momentum I (Worksheet)

( \newcommand{\kernel}{\mathrm{null}\,}\)

Name: ______________________________

Section: _____________________________

Student ID#:__________________________

Work in groups on these problems. You should try to answer the questions without referring to your textbook. If you get stuck, try asking another group for help.

Angular Momentum

We can express the quantum mechanical angular momentum using operators:

ˆLx=ˆyˆpzˆzˆpy=i(yzzy)

ˆLy=ˆzˆpxˆxˆpz=i(zxxz)

ˆLz=ˆxˆpyˆyˆpx=i(xyyx)

ˆL2=ˆL2x+ˆL2y+ˆL2z=2(2x2+2y2+2z2)

Q1

Given these definitions, show that ˆL2 and ˆLx commute.

Use definitions in Cartesian coordinates to show that [ˆLx,ˆLy]=iˆLz, [ˆLy,ˆLz]=iˆLx, [ˆLz,ˆLx]=iˆLy

Define two new Hermitians operators:

  • ˆL+=ˆLx+iˆLy and
  • ˆL=ˆLxiˆLy

Do ˆL+ and ˆL commute with ˆL2? If not, what is the value of the commutator?

Do ˆL+ and ˆL commute with ˆLz? If not, what is the value of the commutator?

Q2

We know that ˆL2Ylm(θ,ϕ)=2l(l+1). Thus, Ylm(θ,ϕ) must also be an eigenfunction of ˆLz. Given that ˆLz=iϕ, show that Ylm(θ,ϕ) is also an eigenfunction for ˆLz by applying it directly. What is the eigenvalue for ˆLzYlm(θ,ϕ)?

Spherical Harmonics
Y0,0(θ,ϕ)=Y00(θ,ϕ)=1(4π)1/2 Y1,0(θ,ϕ)=Y01(θ,ϕ)=3(4π)1/2cosθ
Y1,1(θ,ϕ)=Y11(θ,ϕ)=3(8π)1/2sinθeiϕ Y1,1(θ,ϕ)=Y11(θ,ϕ)=3(8π)1/2sinθeiϕ
Y2,0(θ,ϕ)=Y02(θ,ϕ)=5(16π)1/2(cos2θ1)
Y2,1(θ,ϕ)=Y12(θ,ϕ)=15(8π)1/2sinθcosθeiϕ Y2,1(θ,ϕ)=Y12(θ,ϕ)=15(8π)1/2sinθcosθeiϕ
Y2,2(θ,ϕ)=Y22(θ,ϕ)=15(32π)1/2sin2θe2iϕ Y2,2(θ,ϕ)=Y22(θ,ϕ)=15(32π)1/2sin2θe2iϕ
Y3,0(θ,ϕ)=Y03(θ,ϕ)=15(32π)1/2sin2θ

What is the form of ˆL+ in spherical polar coordinates?

What is the form of ˆL in spherical polar coordinates?

If you apply ˆL+ or ˆL to Ylm(θ,ϕ), what happens?


This page titled Angular Momentum I (Worksheet) is shared under a CC BY-NC-SA 4.0 license and was authored, remixed, and/or curated by Nancy Levinger.

Support Center

How can we help?