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Chemistry LibreTexts

Bridged Bicycloalkane

  • Page ID
    39032
  • A bridged bicycloalkane is a bicycloalkane whose molecule has two carbon atoms shared by all three rings identifiable in the molecule. The two carbon atoms shared by the three rings are called bridgehead carbon atoms. A bond or a chain of bonds connecting the bridgehead carbon atoms is called a bridge.

    eg. 1: Decalin

    eg. 2: bicyclo[2.2.1]heptane

    If in a bridged bicycloalkane, the bridgehead carbons are directly bonded to each other, the compound is called a fused bicycloalkane. In other words, in a fused bicycloalkane, the number of carbon atoms in one of the three bridges is zero. eg: decalin

    see also spirobicycloalkane