Skip to main content
Chemistry LibreTexts

10.1: Emission Spectroscopy Based on Plasma Sources

  • Page ID
    74332
  • \( \newcommand{\vecs}[1]{\overset { \scriptstyle \rightharpoonup} {\mathbf{#1}} } \) \( \newcommand{\vecd}[1]{\overset{-\!-\!\rightharpoonup}{\vphantom{a}\smash {#1}}} \)\(\newcommand{\id}{\mathrm{id}}\) \( \newcommand{\Span}{\mathrm{span}}\) \( \newcommand{\kernel}{\mathrm{null}\,}\) \( \newcommand{\range}{\mathrm{range}\,}\) \( \newcommand{\RealPart}{\mathrm{Re}}\) \( \newcommand{\ImaginaryPart}{\mathrm{Im}}\) \( \newcommand{\Argument}{\mathrm{Arg}}\) \( \newcommand{\norm}[1]{\| #1 \|}\) \( \newcommand{\inner}[2]{\langle #1, #2 \rangle}\) \( \newcommand{\Span}{\mathrm{span}}\) \(\newcommand{\id}{\mathrm{id}}\) \( \newcommand{\Span}{\mathrm{span}}\) \( \newcommand{\kernel}{\mathrm{null}\,}\) \( \newcommand{\range}{\mathrm{range}\,}\) \( \newcommand{\RealPart}{\mathrm{Re}}\) \( \newcommand{\ImaginaryPart}{\mathrm{Im}}\) \( \newcommand{\Argument}{\mathrm{Arg}}\) \( \newcommand{\norm}[1]{\| #1 \|}\) \( \newcommand{\inner}[2]{\langle #1, #2 \rangle}\) \( \newcommand{\Span}{\mathrm{span}}\)\(\newcommand{\AA}{\unicode[.8,0]{x212B}}\)

    • Inductively Coupled Plasma (ICP)
      The inductively coupled plasma (ICP) was developed by Velmer Fassel & Stan Greenfield in the 1960s. It is much hotter than a flame (10,000 K), which causes a high level of ionization for elements with low ionization energy. There is more complete atomization/excitation.
    • Microwave Induced Plasma (MIP)
      A microwave induced plasma is another atomic emission source. Typically, a 2.45 GHz microwave generator (magnetron) produces a wave that travels through a cable and is focused via a tuning system where a torch sits in the center of a cavity. This torch has a carrier gas flowing through the outer portion of the torch (sometimes tangentially, other times not) and the plasma is started (or ignited) via a Tesla coil or a piece of copper wire.
    • Direct Current Plasma (DCP)
      The Direct Current Plasma was developed by William Schrenk over the late 1960s and early 1970s. This emission source utilizes a DC current (40-60 V, 10-15 A, ~750W) which flows between C anodes and W cathode.

    10.1: Emission Spectroscopy Based on Plasma Sources is shared under a CC BY-NC-SA 4.0 license and was authored, remixed, and/or curated by LibreTexts.

    • Was this article helpful?