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  • https://chem.libretexts.org/Bookshelves/Analytical_Chemistry/Supplemental_Modules_(Analytical_Chemistry)/Electrochemistry/Voltaic_Cells
    In redox reactions, electrons are transferred from one species to another. If the reaction is spontaneous, energy is released, which can then be used to do useful work. To harness this energy, the rea...In redox reactions, electrons are transferred from one species to another. If the reaction is spontaneous, energy is released, which can then be used to do useful work. To harness this energy, the reaction must be split into two separate half reactions: the oxidation and reduction reactions. The reactions are put into two different containers and a wire is used to drive the electrons from one side to the other. In doing so, a Voltaic/ Galvanic Cell is created.
  • https://chem.libretexts.org/Bookshelves/Analytical_Chemistry/Supplemental_Modules_(Analytical_Chemistry)/Electrochemistry/Electrolytic_Cells
    Voltaic cells are driven by a spontaneous chemical reaction that produces an electric current through an outside circuit. These cells are important because they are the basis for the batteries that fu...Voltaic cells are driven by a spontaneous chemical reaction that produces an electric current through an outside circuit. These cells are important because they are the basis for the batteries that fuel modern society. But they are not the only kind of electrochemical cell. The reverse reaction in each case is non-spontaneous and requires electrical energy to occur.

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