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21.4: Alpha Halogenation of Carbonyls
https://chem.libretexts.org/Courses/Nassau_Community_College/Organic_Chemistry_I_and_II/21%3A_Alpha_Substitutions_and_Condensations_of_Carbonyl_Compounds/21.04%3A_Alpha_Halogenation_of_Carbonyls
Ketones containing alpha hydrogens can undergo a substitution reaction with halogens under acidic or basic conditions. Aldehydes are oxidized by the halogen before the substitution reaction can occur.

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