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- https://chem.libretexts.org/Courses/East_Tennessee_State_University/CHEM_4110%3A_Advanced_Inorganic_Chemistry/10%3A_Organometallic_Chemistry/10.02%3A_Nomenclature_Ligands_and_Classification/10.2.03%3A_Metal-Carbon_Bonds/10.2.3.02%3A_CarbenesFischer carbenes, Shrock carbenes, and vinylidenes are usually actor ligands, but they may be either nucleophilic or electrophilic, depending on the nature of the R groups and metal. In addition, thes...Fischer carbenes, Shrock carbenes, and vinylidenes are usually actor ligands, but they may be either nucleophilic or electrophilic, depending on the nature of the R groups and metal. In addition, these ligands present some interesting synthetic problems: because free carbenes are quite unstable, ligand substitution does not cut the mustard for metal carbene synthesis.
- https://chem.libretexts.org/Courses/Tennessee_State_University/CHEM_4210%3A_Inorganic_Chem_II_(Siddiquee)/06%3A_Catalysis/6.06%3A_Metal-Carbon_Bonds/6.6.02%3A_CarbenesFischer carbenes, Shrock carbenes, and vinylidenes are usually actor ligands, but they may be either nucleophilic or electrophilic, depending on the nature of the R groups and metal. In addition, thes...Fischer carbenes, Shrock carbenes, and vinylidenes are usually actor ligands, but they may be either nucleophilic or electrophilic, depending on the nature of the R groups and metal. In addition, these ligands present some interesting synthetic problems: because free carbenes are quite unstable, ligand substitution does not cut the mustard for metal carbene synthesis.
- https://chem.libretexts.org/Courses/Ripon_College/CHM_321%3A_Inorganic_Chemistry/06%3A_Organometallic_Chemistry/6.06%3A_Metal-Carbon_Bonds/6.6.02%3A_CarbenesFischer carbenes, Shrock carbenes, and vinylidenes are usually actor ligands, but they may be either nucleophilic or electrophilic, depending on the nature of the R groups and metal. In addition, thes...Fischer carbenes, Shrock carbenes, and vinylidenes are usually actor ligands, but they may be either nucleophilic or electrophilic, depending on the nature of the R groups and metal. In addition, these ligands present some interesting synthetic problems: because free carbenes are quite unstable, ligand substitution does not cut the mustard for metal carbene synthesis.