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- https://chem.libretexts.org/Courses/East_Tennessee_State_University/CHEM_4110%3A_Advanced_Inorganic_Chemistry/10%3A_Organometallic_Chemistry/10.05%3A_Organometallic_Reactions_and_CatalysisIntroduction This chapter is a survey of common organometallic reactions and catalytic cycles. The reactions of organometallic complexes are divided into two main categories: (1) Reactions that involv...Introduction This chapter is a survey of common organometallic reactions and catalytic cycles. The reactions of organometallic complexes are divided into two main categories: (1) Reactions that involve gain or loss of ligands, and (2) Reactions involving modification of ligands.
- https://chem.libretexts.org/Courses/East_Tennessee_State_University/CHEM_4110%3A_Advanced_Inorganic_Chemistry/10%3A_Organometallic_Chemistry/10.07%3A_Organometallic_Catalysts/10.7.01%3A_Catalytic_DeuterationIndustrially, the deuteration is done using a dicyclopentadienyltrihydridotantalum(V) catalyst starting out from benzene and D 2 . The D 2 is provided in excess to drive the chemical equilibrium to th...Industrially, the deuteration is done using a dicyclopentadienyltrihydridotantalum(V) catalyst starting out from benzene and D 2 . The D 2 is provided in excess to drive the chemical equilibrium to the right side. Elimination of H 2 from the Ta(V) catalyst is a reductive elimination (RE) and the re-addition of H 2 to the Ta(III) species an oxidative addition (OA). In the presence of benzene, the Ta(III) species can oxidatively add benzene to form an 18e Ta(V) complex.
- https://chem.libretexts.org/Courses/Kutztown_University_of_Pennsylvania/CHM_320%3A_Advanced_Inorganic_Chemistry_textbook/13%3A_Introduction_to_Organometallic_Complexes/13.04%3A_Reactions_Involving_Gain_or_Loss_of_Ligands
- https://chem.libretexts.org/Courses/Centre_College/CHE_332%3A_Inorganic_Chemistry/11%3A_Organometallic_Reactions_and_Catalysis/11.03%3A_Organometallic_Catalysts/11.3.01%3A_Catalytic_DeuterationIndustrially, the deuteration is done using a dicyclopentadienyltrihydridotantalum(V) catalyst starting out from benzene and D 2 . The D 2 is provided in excess to drive the chemical equilibrium to th...Industrially, the deuteration is done using a dicyclopentadienyltrihydridotantalum(V) catalyst starting out from benzene and D 2 . The D 2 is provided in excess to drive the chemical equilibrium to the right side. Elimination of H 2 from the Ta(V) catalyst is a reductive elimination (RE) and the re-addition of H 2 to the Ta(III) species an oxidative addition (OA). In the presence of benzene, the Ta(III) species can oxidatively add benzene to form an 18e Ta(V) complex.
- https://chem.libretexts.org/Bookshelves/Inorganic_Chemistry/Inorganic_Chemistry_(LibreTexts)/14%3A_Organometallic_Reactions_and_CatalysisIntroduction This chapter is a survey of common organometallic reactions and catalytic cycles. The reactions of organometallic complexes are divided into two main categories: (1) Reactions that involv...Introduction This chapter is a survey of common organometallic reactions and catalytic cycles. The reactions of organometallic complexes are divided into two main categories: (1) Reactions that involve gain or loss of ligands, and (2) Reactions involving modification of ligands.
- https://chem.libretexts.org/Bookshelves/Inorganic_Chemistry/Inorganic_Chemistry_(LibreTexts)/14%3A_Organometallic_Reactions_and_Catalysis/14.03%3A_Organometallic_Catalysts/14.3.01%3A_Catalytic_DeuterationIndustrially, the deuteration is done using a dicyclopentadienyltrihydridotantalum(V) catalyst starting out from benzene and D 2 . The D 2 is provided in excess to drive the chemical equilibrium to th...Industrially, the deuteration is done using a dicyclopentadienyltrihydridotantalum(V) catalyst starting out from benzene and D 2 . The D 2 is provided in excess to drive the chemical equilibrium to the right side. Elimination of H 2 from the Ta(V) catalyst is a reductive elimination (RE) and the re-addition of H 2 to the Ta(III) species an oxidative addition (OA). In the presence of benzene, the Ta(III) species can oxidatively add benzene to form an 18e Ta(V) complex.
- https://chem.libretexts.org/Courses/Ripon_College/CHM_321%3A_Inorganic_Chemistry/07%3A_Organometallic_Reactions_and_Catalysis/7.03%3A_Organometallic_Catalysts/7.3.01%3A_Catalytic_DeuterationIndustrially, the deuteration is done using a dicyclopentadienyltrihydridotantalum(V) catalyst starting out from benzene and D 2 . The D 2 is provided in excess to drive the chemical equilibrium to th...Industrially, the deuteration is done using a dicyclopentadienyltrihydridotantalum(V) catalyst starting out from benzene and D 2 . The D 2 is provided in excess to drive the chemical equilibrium to the right side. Elimination of H 2 from the Ta(V) catalyst is a reductive elimination (RE) and the re-addition of H 2 to the Ta(III) species an oxidative addition (OA). In the presence of benzene, the Ta(III) species can oxidatively add benzene to form an 18e Ta(V) complex.
- https://chem.libretexts.org/Courses/Centre_College/CHE_332%3A_Inorganic_Chemistry/11%3A_Organometallic_Reactions_and_CatalysisIntroduction This chapter is a survey of common organometallic reactions and catalytic cycles. The reactions of organometallic complexes are divided into two main categories: (1) Reactions that involv...Introduction This chapter is a survey of common organometallic reactions and catalytic cycles. The reactions of organometallic complexes are divided into two main categories: (1) Reactions that involve gain or loss of ligands, and (2) Reactions involving modification of ligands.
- https://chem.libretexts.org/Courses/Ripon_College/CHM_321%3A_Inorganic_Chemistry/07%3A_Organometallic_Reactions_and_CatalysisIntroduction This chapter is a survey of common organometallic reactions and catalytic cycles. The reactions of organometallic complexes are divided into two main categories: (1) Reactions that involv...Introduction This chapter is a survey of common organometallic reactions and catalytic cycles. The reactions of organometallic complexes are divided into two main categories: (1) Reactions that involve gain or loss of ligands, and (2) Reactions involving modification of ligands.
- https://chem.libretexts.org/Courses/Saint_Marys_College_Notre_Dame_IN/CHEM_431%3A_Inorganic_Chemistry_(Haas)/CHEM_431_Readings/18%3A_Introduction_to_Organometallic_Complexes/18.04%3A_Reactions_Involving_Gain_or_Loss_of_Ligands
- https://chem.libretexts.org/Courses/Tennessee_State_University/CHEM_4210%3A_Inorganic_Chem_II_(Siddiquee)/07%3A_Organometallic_Reactions_and_Catalysis/7.03%3A_Organometallic_Catalysts/7.3.01%3A_Catalytic_DeuterationIndustrially, the deuteration is done using a dicyclopentadienyltrihydridotantalum(V) catalyst starting out from benzene and D 2 . The D 2 is provided in excess to drive the chemical equilibrium to th...Industrially, the deuteration is done using a dicyclopentadienyltrihydridotantalum(V) catalyst starting out from benzene and D 2 . The D 2 is provided in excess to drive the chemical equilibrium to the right side. Elimination of H 2 from the Ta(V) catalyst is a reductive elimination (RE) and the re-addition of H 2 to the Ta(III) species an oxidative addition (OA). In the presence of benzene, the Ta(III) species can oxidatively add benzene to form an 18e Ta(V) complex.
