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  • https://chem.libretexts.org/Bookshelves/Organic_Chemistry/Basic_Principles_of_Organic_Chemistry_(Roberts_and_Caserio)/08%3A_Nucleophilic_Substitution_and_Elimination_Reactions/8.08%3A_Structural_and_Solvent_Effects_in_(S_N)_Reactions
    We shall consider first the relationship between the structures of alkyl derivatives and their reaction rates toward a given nucleophile. This will be followed by a discussion of the relative reactivi...We shall consider first the relationship between the structures of alkyl derivatives and their reaction rates toward a given nucleophile. This will be followed by a discussion of the relative reactivities of various nucleophiles toward a given alkyl derivative. Finally, we shall comment in more detail on the role of the solvent in nucleophilic substitution reactions.
  • https://chem.libretexts.org/Courses/Winona_State_University/Klein_and_Straumanis_Guided/07%3A_Substitution_Reactions/7.18%3A_7-6_Structural_and_Solvent_Effects_in_(S_N)_Reactions
    We shall consider first the relationship between the structures of alkyl derivatives and their reaction rates toward a given nucleophile. This will be followed by a discussion of the relative reactivi...We shall consider first the relationship between the structures of alkyl derivatives and their reaction rates toward a given nucleophile. This will be followed by a discussion of the relative reactivities of various nucleophiles toward a given alkyl derivative. Finally, we shall comment in more detail on the role of the solvent in nucleophilic substitution reactions.