A metal ion in solution does not exist in isolation, but in combination with ligands (such as solvent molecules or simple ions) or chelating groups, giving rise to complex ions or coordination compoun...A metal ion in solution does not exist in isolation, but in combination with ligands (such as solvent molecules or simple ions) or chelating groups, giving rise to complex ions or coordination compounds. These complexes contain a central atom or ion, often a transition metal, and a cluster of ions or neutral molecules surrounding it. Ligands are ions or neutral molecules that bond to a central metal atom or ion. Ligands act as Lewis bases and the central atom acts as a Lewis acid.