This page discusses the deviations from ideal gas behavior and introduces the van der Waals equation, which provides corrections for these deviations by considering intermolecular interactions and mol...This page discusses the deviations from ideal gas behavior and introduces the van der Waals equation, which provides corrections for these deviations by considering intermolecular interactions and molecular size. It presents the van der Waals constants for different gases and mentions other equations of state like Redlich-Kwong and Dieterici that account for temperature dependence. The Virial Equation is introduced as another way to account for deviations from ideal behavior.
The idea and basis for this is that with metal and hydrogen bonding there is a crystal lattice that H atoms can and may fill in between the lattice while some might, and is not a definite ordered fill...The idea and basis for this is that with metal and hydrogen bonding there is a crystal lattice that H atoms can and may fill in between the lattice while some might, and is not a definite ordered filling. Due to the hydrogen bonds of the three following hydrides, they distinctly have high boiling points instead of the initial assumption of having the lowest boiling points.
