Search
- https://chem.libretexts.org/Courses/Los_Angeles_Trade_Technical_College/Analytical_Chemistry/2%3A_Analytical_Chemistry_2.0_(Harvey)/14%3A_Kinetic_Methods/14.2%3A_Chemical_KineticsEvery chemical reaction occurs at a finite rate, making it a potential candidate for a chemical kinetic method of analysis. To be effective, however, the chemical reaction must meet three necessary co...Every chemical reaction occurs at a finite rate, making it a potential candidate for a chemical kinetic method of analysis. To be effective, however, the chemical reaction must meet three necessary conditions: the reaction must not occur too quickly or too slowly; we must know the reaction’s rate law; and we must be able to monitor the change in concentration for at least one species.
- https://chem.libretexts.org/Courses/Western_Washington_University/Biophysical_Chemistry_(Smirnov_and_McCarty)/02%3A_Chemical_Kinetics/2.03%3A_Transition_State_TheoryThus far we have not considered the temperature dependence of the rate. Temperature affects a reaction rate because the rate ???constant??? k k that enters into the rate equation is temperature dep...Thus far we have not considered the temperature dependence of the rate. Temperature affects a reaction rate because the rate ???constant??? k k that enters into the rate equation is temperature dependent. Typically, the rate of a reaction will increase with temperature because a higher kinetic energy leads to more molecular collisions with sufficient orientation and energy. However, for enzyme-catalyzed reactions, a higher temperature can lead to a decrease in the rate as the enzyme denatures
- https://chem.libretexts.org/Bookshelves/Analytical_Chemistry/Analytical_Chemistry_2.1_(Harvey)/13%3A_Kinetic_Methods/13.02%3A_Chemical_KineticsThe earliest analytical methods based on chemical kinetics???which first appear in the late nineteenth century???took advantage of the catalytic activity of enzymes. Despite the diversity of chemical ...The earliest analytical methods based on chemical kinetics???which first appear in the late nineteenth century???took advantage of the catalytic activity of enzymes. Despite the diversity of chemical kinetic methods, by 1960 they no longer were in common use. By the 1980s, improvements in instrumentation and data analysis methods compensated for these limitations, ensuring the further development of chemical kinetic methods of analysis.
