As outlined below, the Henderson–Hasselbalch approximation provides a simple way to calculate the pH of a buffer, and to determine the change in pH upon adding a strong acid or strong base.
The buffer capacity is the amount (mol) of acid or base that can be added to a given volume of a buffer solution before the pH changes by ±1 from the pK a of the weak acid. (Recall that if equal conce...The buffer capacity is the amount (mol) of acid or base that can be added to a given volume of a buffer solution before the pH changes by ±1 from the pK a of the weak acid. (Recall that if equal concentrations of weak acid and conjugate base are in a buffer solution, pH = pK a .)
As outlined below, the Henderson–Hasselbalch approximation provides a simple way to calculate the pH of a buffer, and to determine the change in pH upon adding a strong acid or strong base.
This page explains the different responses to adding HCl to pure water versus a solution with acetic acid and sodium acetate. It describes how buffers, like the acetic acid-sodium acetate mixture, res...This page explains the different responses to adding HCl to pure water versus a solution with acetic acid and sodium acetate. It describes how buffers, like the acetic acid-sodium acetate mixture, resist changes in pH due to their equilibrium shifting. The Henderson-Hasselbalch equation is central to understanding buffer preparation and effectiveness.