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- https://chem.libretexts.org/Bookshelves/Organic_Chemistry/Organic_Chemistry_I_(Liu)/10%3A_Alkenes_and_Alkynes/10.09%3A_Answers_to_Practice_Questions_Chapter_1010.1 Show structure of the major product for following addition reactions. 10.2 For the addition of HBr to 3-methyl-1-butene, two products were observed. Show the reaction mechanism to explain the for...10.1 Show structure of the major product for following addition reactions. 10.2 For the addition of HBr to 3-methyl-1-butene, two products were observed. Show the reaction mechanism to explain the formation of both products. Mechanism: 10.3 Show major product(s) for the following reactions. 10.4 Show major product(s) of the following reactions.
- https://chem.libretexts.org/Bookshelves/Organic_Chemistry/Organic_Chemistry_I_(Liu)/00%3A_Front_Matter/02%3A_InfoPageThe LibreTexts libraries are Powered by MindTouch ® and are supported by the Department of Education Open Textbook Pilot Project, the UC Davis Office of the Provost, the UC Davis Library, the Californ...The LibreTexts libraries are Powered by MindTouch ® and are supported by the Department of Education Open Textbook Pilot Project, the UC Davis Office of the Provost, the UC Davis Library, the California State University Affordable Learning Solutions Program, and Merlot.
- https://chem.libretexts.org/Bookshelves/Organic_Chemistry/Organic_Chemistry_I_(Liu)/05%3A_StereochemistryThumbnail: Two enantiomers of a generic amino acid that are chiral. (Public Domain; unknonw author via Wikipedia)
- https://chem.libretexts.org/Bookshelves/Organic_Chemistry/Organic_Chemistry_I_(Liu)/09%3A_Free_Radical_Substitution_Reaction_of_Alkanes
- https://chem.libretexts.org/Bookshelves/Organic_Chemistry/Organic_Chemistry_I_(Liu)/09%3A_Free_Radical_Substitution_Reaction_of_Alkanes/9.05%3A_Stereochemistry_for_Halogenation_of_AlkanesHowever, experiment evidence indicate that the geometric shape of most alkyl radical is trigonal planar shape, with the carbon in sp 2 hybridization, and there is one single unpaired electron in the u...However, experiment evidence indicate that the geometric shape of most alkyl radical is trigonal planar shape, with the carbon in sp 2 hybridization, and there is one single unpaired electron in the unhybridized 2p orbital. Because both sides are identical, the probability of the reaction by either side is the same, therefore equal amount of the R– and S– enantiomer are obtained as a racemic mixture.
- https://chem.libretexts.org/Bookshelves/Organic_Chemistry/Organic_Chemistry_I_(Liu)/03%3A_Acids_and_Bases-_Organic_Reaction_Mechanism_Introduction/3.03%3A_pKa_of_Organic_Acids_and_Application_of_pKa_to_Predict_Acid-Base_Reaction_OutcomeThe acidity of the functional groups in the table decreases from top to the bottom, and the basicity of the conjugate bases in the last column increases from top to bottom, because the stronger the ac...The acidity of the functional groups in the table decreases from top to the bottom, and the basicity of the conjugate bases in the last column increases from top to bottom, because the stronger the acid, the weaker the conjugate base is. With pK a values available at hand, the relative acidity of reactants vs products can be compared by comparing their pK a values, and the reaction will proceed to the side of the acid with a larger pK a (larger pK a means smaller K a , therefore weaker acid).
- https://chem.libretexts.org/Bookshelves/Organic_Chemistry/Organic_Chemistry_I_(Liu)/05%3A_Stereochemistry/5.06%3A_Compounds_with_More_Than_One_Chirality_CentersThe relationship between any of the cis-isomer to any of the trans-isomer is diastereomers (A and C, A and D, B and C, B and D). For the meso isomer of 2,3-dichlorobutane, the plane of symmetry is the...The relationship between any of the cis-isomer to any of the trans-isomer is diastereomers (A and C, A and D, B and C, B and D). For the meso isomer of 2,3-dichlorobutane, the plane of symmetry is the plane that is labelled in the structure below. Let’s rotate the groups around the 2 nd chirality centre of structure I (you can use the molecular model to do the rotation, that is very helpful for visualizing the spatial arrangement of the groups):
- https://chem.libretexts.org/Bookshelves/Organic_Chemistry/Organic_Chemistry_I_(Liu)An open textbook that is suitable for the first semester of Organic Chemistry. Basic concepts of the structures and reactivities of organic molecules are covered in this open textbook. Besides the fun...An open textbook that is suitable for the first semester of Organic Chemistry. Basic concepts of the structures and reactivities of organic molecules are covered in this open textbook. Besides the fundamental discussions of organic acids-bases, stereochemistry, IR and NMR, this book also includes the topics of substitution and elimination reactions, radical substitution of alkanes, preparation and reactions of alkenes and alkynes.
- https://chem.libretexts.org/Bookshelves/Organic_Chemistry/Organic_Chemistry_I_(Liu)/02%3A_Fundamental_of_Organic_Structures
- https://chem.libretexts.org/Bookshelves/Organic_Chemistry/Organic_Chemistry_I_(Liu)/00%3A_Front_Matter
- https://chem.libretexts.org/Bookshelves/Organic_Chemistry/Organic_Chemistry_I_(Liu)/08%3A_Elimination_Reactions/8.02%3A_E1_ReactionFor E1 reaction, if more than one alkenes could be possibly formed as product, the major product will also be the more substituted alkene, like E2, because of the stability of those alkenes. For the f...For E1 reaction, if more than one alkenes could be possibly formed as product, the major product will also be the more substituted alkene, like E2, because of the stability of those alkenes. For the following example, the initially formed secondary carbocation undergoes a 1,2-methanide shift to give the more stable tertiary benzylic carbocation, that lead to the final elimination product.
