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  • https://chem.libretexts.org/Bookshelves/Inorganic_Chemistry/Map%3A_Inorganic_Chemistry_(Housecroft)/10%3A_Hydrogen/10.07%3A_Binary_Hydrides_-_Classification_and_General_Properties/10.7B%3A_Metallic_Hydrides
    Metallic hydrides (also known as interstitial hydrides) involve hydrogen bonds with transition metals. One interesting and unique characteristic of these hydrides are that they can be nonstoichiometri...Metallic hydrides (also known as interstitial hydrides) involve hydrogen bonds with transition metals. One interesting and unique characteristic of these hydrides are that they can be nonstoichiometric, meaning basically that the fraction of H atoms to the metals are not fixed. Nonstoichiometric compounds have a variable composition. The idea and basis for this is that with metal and hydrogen bonding there is a crystal lattice that H atoms can and may fill in between the lattice.
  • https://chem.libretexts.org/Bookshelves/Inorganic_Chemistry/Supplemental_Modules_and_Websites_(Inorganic_Chemistry)/Descriptive_Chemistry/Main_Group_Reactions/Compounds/Hydrides
    The idea and basis for this is that with metal and hydrogen bonding there is a crystal lattice that H atoms can and may fill in between the lattice while some might, and is not a definite ordered fill...The idea and basis for this is that with metal and hydrogen bonding there is a crystal lattice that H atoms can and may fill in between the lattice while some might, and is not a definite ordered filling. Due to the hydrogen bonds of the three following hydrides, they distinctly have high boiling points instead of the initial assumption of having the lowest boiling points.

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