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  • https://chem.libretexts.org/Bookshelves/General_Chemistry/General_Chemistry_Supplement_(Eames)/Solids/Ionic_Solids
    The key thing is that the number of cations and anions in the unit cell is the same as the overall formula, and, for example, if the formula is AB 2 , then the coordination number of A is double the c...The key thing is that the number of cations and anions in the unit cell is the same as the overall formula, and, for example, if the formula is AB 2 , then the coordination number of A is double the coordination number of B. The main thing to know is that the smaller the ions and the larger the charge, the bigger the lattice energy is, and the more stable the solid.
  • https://chem.libretexts.org/Courses/Centre_College/CHE_332%3A_Inorganic_Chemistry/09%3A_Structure_and_Energetics_of_Solids
    In this chapter we will try to systematize the structures of inorganic solids - metal oxides, halides, sulfides, and related compounds - and develop some rules for which structures to expect based on ...In this chapter we will try to systematize the structures of inorganic solids - metal oxides, halides, sulfides, and related compounds - and develop some rules for which structures to expect based on electronegativity differences, hard-soft acid-base rules, and other periodic trends. Figure \PageIndex2: The morphology of twinned crystals of iron pyrite (FeS 2 ) is related to the underlying cubic symmetry of the unit cell.
  • https://chem.libretexts.org/Courses/East_Tennessee_State_University/CHEM_3110%3A_Descriptive_Inorganic_Chemistry/05%3A_Structure_and_Energetics_of_Solids
    In this chapter we will try to systematize the structures of inorganic solids - metal oxides, halides, sulfides, and related compounds - and develop some rules for which structures to expect based on ...In this chapter we will try to systematize the structures of inorganic solids - metal oxides, halides, sulfides, and related compounds - and develop some rules for which structures to expect based on electronegativity differences, hard-soft acid-base rules, and other periodic trends. Figure \PageIndex2: The morphology of twinned crystals of iron pyrite (FeS 2 ) is related to the underlying cubic symmetry of the unit cell.

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