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- https://chem.libretexts.org/Courses/Alma_College/Organic_Chemistry_I_(Alma_College)/10%3A_Alkenes-_Structure_and_Reactivity/10.11%3A_Evidence_for_the_Mechanism_of_Electrophilic_Additions_-_Carbocation_RearrangementsWhenever possible, carbocations will rearrange from a less stable isomer to a more stable isomer. This rearrangement can be achieved by either a hydride shift, where a hydrogen atom migrates from one ...Whenever possible, carbocations will rearrange from a less stable isomer to a more stable isomer. This rearrangement can be achieved by either a hydride shift, where a hydrogen atom migrates from one carbon atom to the next, taking a pair of electrons with it; or an alkyl shift, in which an alkyl group undergoes a similar migration, again taking a bonding pair of electrons with it. These migrations usually occur between neighboring carbon atoms.
- https://chem.libretexts.org/Bookshelves/Organic_Chemistry/Organic_Chemistry_(Morsch_et_al.)/07%3A_Alkenes-_Structure_and_Reactivity/7.12%3A_Evidence_for_the_Mechanism_of_Electrophilic_Additions_-_Carbocation_RearrangementsWhenever possible, carbocations will rearrange from a less stable isomer to a more stable isomer. This rearrangement can be achieved by either a hydride shift, where a hydrogen atom migrates from one ...Whenever possible, carbocations will rearrange from a less stable isomer to a more stable isomer. This rearrangement can be achieved by either a hydride shift, where a hydrogen atom migrates from one carbon atom to the next, taking a pair of electrons with it; or an alkyl shift, in which an alkyl group undergoes a similar migration, again taking a bonding pair of electrons with it. These migrations usually occur between neighboring carbon atoms.
- https://chem.libretexts.org/Bookshelves/Organic_Chemistry/Supplemental_Modules_(Organic_Chemistry)/Reactions/Elimination_Reactions/E1_Reactions/Carbocation_RearrangementsBefore the Cl atom attacks, the hydrogen atom attached to the Carbon atom directly adjacent to the original Carbon (preferably the more stable Carbon), Carbon #2, can undergo hydride shift. After prot...Before the Cl atom attacks, the hydrogen atom attached to the Carbon atom directly adjacent to the original Carbon (preferably the more stable Carbon), Carbon #2, can undergo hydride shift. After protonating the alcohol substrate to form the alkyloxonium ion, the water must leave at the same time as the alkyl group shifts from the adjacent carbon to skip the formation of the unstable primary carbocation.
- https://chem.libretexts.org/Courses/Smith_College/Organic_Chemistry_(LibreTexts)/07%3A_Alkenes-_Structure_and_Reactivity/7.13%3A_Evidence_for_the_Mechanism_of_Electrophilic_Additions_-_Carbocation_RearrangementsWhenever possible, carbocations will rearrange from a less stable isomer to a more stable isomer. This rearrangement can be achieved by either a hydride shift, where a hydrogen atom migrates from one ...Whenever possible, carbocations will rearrange from a less stable isomer to a more stable isomer. This rearrangement can be achieved by either a hydride shift, where a hydrogen atom migrates from one carbon atom to the next, taking a pair of electrons with it; or an alkyl shift, in which an alkyl group undergoes a similar migration, again taking a bonding pair of electrons with it. These migrations usually occur between neighboring carbon atoms.
- https://chem.libretexts.org/Bookshelves/Organic_Chemistry/Organic_Chemistry_(OpenStax)/07%3A_Alkenes-_Structure_and_Reactivity/7.11%3A_Evidence_for_the_Mechanism_of_Electrophilic_Additions_-_Carbocation_RearrangementsWhenever possible, carbocations will rearrange from a less stable isomer to a more stable isomer. This rearrangement can be achieved by either a hydride shift, where a hydrogen atom migrates from one ...Whenever possible, carbocations will rearrange from a less stable isomer to a more stable isomer. This rearrangement can be achieved by either a hydride shift, where a hydrogen atom migrates from one carbon atom to the next, taking a pair of electrons with it; or an alkyl shift, in which an alkyl group undergoes a similar migration, again taking a bonding pair of electrons with it. These migrations usually occur between neighboring carbon atoms.
- https://chem.libretexts.org/Ancillary_Materials/Reference/Organic_Chemistry_Glossary/12-Alkyl_ShiftA 1,2-alkyl shift is a carbocation rearrangement in which an alkyl group migrates to the carbon atom bearing the formal charge of +1 (carbon 2) from an adjacent carbon atom (carbon 1).
- https://chem.libretexts.org/Courses/can/CHEM_231%3A_Organic_Chemistry_I_Textbook/07%3A_Alkenes-_Structure_and_Reactivity/7.11%3A_Evidence_for_the_Mechanism_of_Electrophilic_Additions_-_Carbocation_RearrangementsWhenever possible, carbocations will rearrange from a less stable isomer to a more stable isomer. This rearrangement can be achieved by either a hydride shift, where a hydrogen atom migrates from one ...Whenever possible, carbocations will rearrange from a less stable isomer to a more stable isomer. This rearrangement can be achieved by either a hydride shift, where a hydrogen atom migrates from one carbon atom to the next, taking a pair of electrons with it; or an alkyl shift, in which an alkyl group undergoes a similar migration, again taking a bonding pair of electrons with it. These migrations usually occur between neighboring carbon atoms.
- https://chem.libretexts.org/Workbench/LCDS_Organic_Chemistry_OER_Textbook_-_Todd_Trout/07%3A_Alkenes-_Structure_and_Reactivity/7.12%3A_Evidence_for_the_Mechanism_of_Electrophilic_Additions_-_Carbocation_RearrangementsWhenever possible, carbocations will rearrange from a less stable isomer to a more stable isomer. This rearrangement can be achieved by either a hydride shift, where a hydrogen atom migrates from one ...Whenever possible, carbocations will rearrange from a less stable isomer to a more stable isomer. This rearrangement can be achieved by either a hydride shift, where a hydrogen atom migrates from one carbon atom to the next, taking a pair of electrons with it; or an alkyl shift, in which an alkyl group undergoes a similar migration, again taking a bonding pair of electrons with it. These migrations usually occur between neighboring carbon atoms.
- https://chem.libretexts.org/Workbench/Community_College_of_Baltimore_County_Organic_Chemistry_1/08%3A_Alkenes-_Structure_and_Reactivity/8.15%3A_Evidence_for_the_Mechanism_of_Electrophilic_Additions_-_Carbocation_RearrangementsWhenever possible, carbocations will rearrange from a less stable isomer to a more stable isomer. This rearrangement can be achieved by either a hydride shift, where a hydrogen atom migrates from one ...Whenever possible, carbocations will rearrange from a less stable isomer to a more stable isomer. This rearrangement can be achieved by either a hydride shift, where a hydrogen atom migrates from one carbon atom to the next, taking a pair of electrons with it; or an alkyl shift, in which an alkyl group undergoes a similar migration, again taking a bonding pair of electrons with it. These migrations usually occur between neighboring carbon atoms.
- https://chem.libretexts.org/Bookshelves/Organic_Chemistry/Organic_Chemistry_I_(Morsch_et_al.)/07%3A_Alkenes_-_Structure_and_Reactivity/7.12%3A_Evidence_for_the_Mechanism_of_Electrophilic_Additions_-_Carbocation_RearrangementsWhenever possible, carbocations will rearrange from a less stable isomer to a more stable isomer. This rearrangement can be achieved by either a hydride shift, where a hydrogen atom migrates from one ...Whenever possible, carbocations will rearrange from a less stable isomer to a more stable isomer. This rearrangement can be achieved by either a hydride shift, where a hydrogen atom migrates from one carbon atom to the next, taking a pair of electrons with it; or an alkyl shift, in which an alkyl group undergoes a similar migration, again taking a bonding pair of electrons with it. These migrations usually occur between neighboring carbon atoms.
- https://chem.libretexts.org/Courses/Smith_College/CHM_222_Chemistry_II%3A_Organic_Chemistry_(2025)/14%3A_Alkenes-_Structure_and_Reactivity/14.13%3A_Evidence_for_the_Mechanism_of_Electrophilic_Additions_-_Carbocation_RearrangementsWhenever possible, carbocations will rearrange from a less stable isomer to a more stable isomer. This rearrangement can be achieved by either a hydride shift, where a hydrogen atom migrates from one ...Whenever possible, carbocations will rearrange from a less stable isomer to a more stable isomer. This rearrangement can be achieved by either a hydride shift, where a hydrogen atom migrates from one carbon atom to the next, taking a pair of electrons with it; or an alkyl shift, in which an alkyl group undergoes a similar migration, again taking a bonding pair of electrons with it. These migrations usually occur between neighboring carbon atoms.
