5.4: Polyatomic MO Diagrams

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Jan 17, 2025
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- 5.3.2.3: Ionic Compounds and Molecular Orbitals
- 5.4.1: Ligand Group Orbitals and Generator Functions

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Learning objectives for this unit are to:

Use group theory and the central atom generator function method to determine the symmetries of and draw pictures of ligand group orbitals (LGOs)
Derive molecular orbital energy diagrams for polyatomic molecules based on the interactions between the central atom AOs and the LGOs
Use MO diagrams to determine or rationalize bond order (bond length/strength), magnetism, and reactivity of molecules
Generate and interpret Walsh correlation diagrams for two different geometric arrangements of atoms

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