UCD Chem 2BH: Larsen
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- AGENDA
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- Unit 1: Chemical Thermodynamics
- I: Fundamentals of Thermochemistry (Heat and Enthalpy)
- 1.1: Systems, States and Processes
- 1.2: Heat
- 1.3: Work
- 1.4: The First Law of Thermodynamics
- 1.5: Heat Capacity and Calorimetry
- 1.6: Molecules as Energy Carriers and Converters
- 1.7: Heats of Reactions - ΔU and ΔH
- 1.8: Indirect Determination of ΔH - Hess's Law
- 1.10: Fuels as Sources of Energy
- 1.9: Standard Enthalpies of Formation
- 1.E: Fundamentals of Thermochemistry (Exercises)
- II: Principles of Thermodynamics (Entropy and Gibbs Energy)
- 2.1: The Nature of Spontaneous Processes
- 2.2: Entropy and Spontaneity - A Molecular Statistical Interpretation
- 2.3: Entropy and Heat - Experimental Basis of the Second Law of Thermodynamics
- 2.4: Entropy Changes and Spontaneity
- 2.5: Entropy Changes in Reversible Processes
- 2.6: Quantum States, Microstates, and Energy Spreading
- 2.7: The Third Law of Thermodynamics
- 2.8: Gibbs Energy
- 2.E: Principles of Thermodynamics (Exercises)
- I: Fundamentals of Thermochemistry (Heat and Enthalpy)
- Unit II: Physical Equilibria
- III: Solids, Liquids, and Phase Transitions
- 3.1: Bulk Properties of Gases, Liquids, and Solids - Molecular Interpretation
- 3.2: Intermolecular Forces - Origins in Molecular Structure
- 3.3: Intermolecular Forces in Liquids
- 3.4: Phase Equilibrium
- 3.5: Phase Transitions
- 3.6: Phase Diagrams
- 3.7: Clausius-Clapeyron Equation
- 3.8: The Solid State
- 3.9: Bonding in Metals
- 3.E: Solids, Liquids, and Phase Transitions (Exercises)
- IV: Solutions
- 4.0: Types of Solutions - Some Terminology
- 4.1: Composition of Solutions
- 4.2: Nature of Dissolved Species
- 4.3: Phase Equilibrium in Solutions - Nonvolatile Solutes
- 4.4: Phase Equilibrium in Solutions - Volatile Solutes
- 4.5: Separating Volatile Solutions - Distillation
- 4.6: Colloidal Suspensions
- 4.E: Solutions (Exercises)
- III: Solids, Liquids, and Phase Transitions
- Unit III: Chemical Equilibria
- V: Chemical Equilibrium
- 5.1: The Nature of Chemical Equilibrium
- 5.2: The Empirical Law of Mass Action
- 5.3: Thermodynamic Description of the Equilibrium State
- 5.4: The Law of Mass Action for Related and Simultaneous Equilibria
- 5.5: Gas-Phase and Heterogeneous Reaction Equilibria
- 5.6: The Direction of Change in Chemical Reactions: Empirical Description
- 5.7: The Direction of Change in Chemical Reactions - Thermodynamic Explanation
- 5.8: Distribution between Immiscible Phases - Extraction and Separation Processes
- 5.E: Chemical Equilibrium (Exercises)
- VI: Acid–Base Equilibria
- 6.1: Classifications of Acids and Bases
- 6.2: The Brønsted-Lowry Scheme
- 6.3: Acid and Base Strength
- 6.4: Equilibria Involving Weak Acids and Bases
- 6.5: Buffer Solutions
- 6.6: Acid-Base Titration Curves
- 6.7: Polyprotic Acids
- 6.8: A Deeper Look - Exact Treatment of Acid-Base Equilibria
- 6.9: Organic Acids and Bases - Structure and Reactivity
- 6.10: Lewis Bases as Nucleophilic Reactants in Organic Reactions
- VII: Solubility and Precipitation Equilibria
- V: Chemical Equilibrium
- Unit 1: Chemical Thermodynamics
- Homework
- (old) Comprehensive Homework Questions for Exam 2
- Comprehensive Equilibrium Homework (Extra Problems)
- Comprehensive Homework 1 (Due 1/14/2019)
- Comprehensive Homework 2 (Due 1/22/2019)
- Comprehensive Homework 3 (Due 1/28/2018)
- Comprehensive Homework 4 (Due 2/4/2018)
- Comprehensive Homework 5 (Due 2/15/2019)
- Comprehensive Homework 6 (Due 2/21/2019) @ noon
- Comprehensive Homework 7 (Due 3/4/2019)
- Comprehensive Homework 8 (Due 3/11/2019)
- Comprehensive Homework 9 (Due 3/15/2019)
- Example Final Conceptual Questions
- Example Midterm 1 Questions
- Example Midterm 2 Questions
- Extra Credit Homework 1 (1/25/2019)
- Extra Credit Homework 2 (2/5/2019)
- Extra Credit Homework 3 (2/18/2019)
- Extra Credit Homework 4 (3/8/2019)
- Mini-Homework 1 (Due 2/1/2019)
- Mini-Homework 2 (Due 2/11/2019)
- Mini-Homework 3 (Due 2/13/2019)
- Mini-Homework 4 (2/28/19)
- Mini-Homework 5 (3/1/19)
- Mini-Homework 6 (3/6/19)
- Mini-Homework 7 (3/8/19)
- Mini-Homework 8 (3/13/19)
- Worksheets
- 1: Thermochemistry I (Worksheet)
- 2: Thermochemistry II (Worksheet)
- 3A: Entropy and Probability (Worksheet)
- 3B: Second & Third Laws of Thermodynamics (Worksheet)
- 4: Intermolecular Forces and Interactions (Worksheet)
- 5A: Pure Phases and their Transitions (Worksheet)
- 5B: Solutions and Vapor Pressures (Worksheet)
- 6: Colligative Properties (Worksheet)
- 7: Equilibria, Equilibrium Constants and Acid-Bases (Worksheet)
- 8: ICE Tables (Worksheet)
- 9: Acids/Bases, Common Ion Effect, and Buffers (Worksheet)
- 10: Weak Acid and Base Equilibria (Worksheet)
- Chem 2BH: Laboratory Manual
- Preface and Lab Details
- 1: Thermochemistry (Experiment)
- 2: Standardization of Acids and Bases (Experiment)
- 3: Analysis of a Commercial Antacid (Experiment)
- 4: Determination of the Molar Mass by Freezing Point Depression (Experiment)
- 5: Le Chatelier's Principle (Experiment)
- 6: Determination of Kc for a Complex Ion Formation (Experiment)
Condensed phases and intermolecular forces, chemical thermodynamics, chemical equilibria, acids and bases, solubility. Laboratory experiments in thermochemistry, equilibria, and quantitative analysis using volumetric methods.