11.6: Water is Both an Acid and a Base
- Page ID
- 33975
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- To write chemical equations for water acting as an acid and as a base.
Water (H2O) is an interesting compound in many respects. Here, we will consider its ability to behave as an acid or a base.
In some circumstances, a water molecule will accept a proton and thus act as a Brønsted-Lowry base. We saw an example in the dissolving of HCl in H2O:
\[\rm{HCl + H_2O_{(ℓ)} \rightarrow H_3O^+_{(aq)} + Cl^−_{(aq)}} \tag{11.6.1}\]
In other circumstances, a water molecule can donate a proton and thus act as a Brønsted-Lowry acid. For example, in the presence of the amide ion (see Example 4 in Section 10.2), a water molecule donates a proton, making ammonia as a product:
\[H_2O_{(ℓ)} + NH^−_{2(aq)} \rightarrow OH^−_{(aq)} + NH_{3(aq)} \tag{11.6.2}\]
In this case, NH2− is a Brønsted-Lowry base (the proton acceptor).
So, depending on the circumstances, H2O can act as either a Brønsted-Lowry acid or a Brønsted-Lowry base. Water is not the only substance that can react as an acid in some cases or a base in others, but it is certainly the most common example—and the most important one. A substance that can either donate or accept a proton, depending on the circumstances, is called an amphiprotic compound.
A water molecule can act as an acid or a base even in a sample of pure water. About 6 in every 100 million (6 in 108) water molecules undergo the following reaction:
\[H_2O_{(ℓ)} + H_2O_{(ℓ)} \rightarrow H_3O^+_{(aq)} + OH^−_{(aq)} \tag{11.6.3}\]
This process is called the autoionization of water (Figure 11.6.1) and occurs in every sample of water, whether it is pure or part of a solution. Autoionization occurs to some extent in any amphiprotic liquid. (For comparison, liquid ammonia undergoes autoionization as well, but only about 1 molecule in a million billion (1 in 1015) reacts with another ammonia molecule.)
Figure 11.6.1 Autoionization. A small fraction of water molecules—approximately 6 in 100 million—ionize spontaneously into hydronium ions and hydroxide ions. This picture necessarily overrepresents the amount of autoionization that really occurs in pure water.
Example 11.6.1
Identify water as either a Brønsted-Lowry acid or a Brønsted-Lowry base.
- H2O(ℓ) + NO2−(aq) → HNO2(aq) + OH−(aq)
- HC2H3O2(aq) + H2O(ℓ) → H3O+(aq) + C2H3O2−(aq)
SOLUTION
- In this reaction, the water molecule donates a proton to the NO2− ion, making OH−(aq). As the proton donor, H2O acts as a Brønsted-Lowry acid.
- In this reaction, the water molecule accepts a proton from HC2H3O2, becoming H3O+(aq). As the proton acceptor, H2O is a Brønsted-Lowry base.
Exercise 11.6.2
Identify water as either a Brønsted-Lowry acid or a Brønsted-Lowry base.
- HCOOH(aq) + H2O(ℓ) → H3O+(aq) + HCOO−(aq)
- H2O(ℓ) + PO43−(aq) → OH−(aq) + HPO42−(aq)
Concept Review Exercises
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Explain how water can act as an acid.
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Explain how water can act as a base.
Answers
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Under the right conditions, H2O can donate a proton, making it a Brønsted-Lowry acid.
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Under the right conditions, H2O can accept a proton, making it a Brønsted-Lowry base.
Key Takeaway
- Water molecules can act as both an acid and a base, depending on the conditions.
Exercises
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Is H2O(ℓ) acting as an acid or a base?
H2O(ℓ) + NH4+(aq) → H3O+(aq) + NH3(aq)
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Is H2O(ℓ) acting as an acid or a base?
CH3−(aq) + H2O(ℓ) → CH4(aq) + OH−(aq)
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In the aqueous solutions of some salts, one of the ions from the salt can react with water molecules. In some C2H3O2− solutions, the following reaction can occur:
C2H3O2−(aq) + H2O(ℓ) → HC2H3O2(aq) + OH−(aq)
Is H2O acting as an acid or a base in this reaction?
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In the aqueous solutions of some salts, one of the ions from the salt can react with water molecules. In some NH4+ solutions, the following reaction can occur:
NH4+(aq) + H2O → NH3(aq) + H3O+(aq)
Is H2O acting as an acid or a base in this reaction?
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Aluminum hydroxide [Al(OH)3] is amphoteric; it reacts with both acids and bases. Propose the chemical equations for the reactions of Al(OH)3 with H+ and with OH−.
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Based on the information in this section, does ammonia (NH3) autoionize more or less than water? Write the chemical equation for the autoionization of ammonia.
Answers
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base
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acid
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Al(OH)3 + H+ → HAl(OH)3+; Al(OH)3 + OH− → Al(OH)4−