10.E: Exercises
- Page ID
- 465668
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\(\newcommand{\avec}{\mathbf a}\) \(\newcommand{\bvec}{\mathbf b}\) \(\newcommand{\cvec}{\mathbf c}\) \(\newcommand{\dvec}{\mathbf d}\) \(\newcommand{\dtil}{\widetilde{\mathbf d}}\) \(\newcommand{\evec}{\mathbf e}\) \(\newcommand{\fvec}{\mathbf f}\) \(\newcommand{\nvec}{\mathbf n}\) \(\newcommand{\pvec}{\mathbf p}\) \(\newcommand{\qvec}{\mathbf q}\) \(\newcommand{\svec}{\mathbf s}\) \(\newcommand{\tvec}{\mathbf t}\) \(\newcommand{\uvec}{\mathbf u}\) \(\newcommand{\vvec}{\mathbf v}\) \(\newcommand{\wvec}{\mathbf w}\) \(\newcommand{\xvec}{\mathbf x}\) \(\newcommand{\yvec}{\mathbf y}\) \(\newcommand{\zvec}{\mathbf z}\) \(\newcommand{\rvec}{\mathbf r}\) \(\newcommand{\mvec}{\mathbf m}\) \(\newcommand{\zerovec}{\mathbf 0}\) \(\newcommand{\onevec}{\mathbf 1}\) \(\newcommand{\real}{\mathbb R}\) \(\newcommand{\twovec}[2]{\left[\begin{array}{r}#1 \\ #2 \end{array}\right]}\) \(\newcommand{\ctwovec}[2]{\left[\begin{array}{c}#1 \\ #2 \end{array}\right]}\) \(\newcommand{\threevec}[3]{\left[\begin{array}{r}#1 \\ #2 \\ #3 \end{array}\right]}\) \(\newcommand{\cthreevec}[3]{\left[\begin{array}{c}#1 \\ #2 \\ #3 \end{array}\right]}\) \(\newcommand{\fourvec}[4]{\left[\begin{array}{r}#1 \\ #2 \\ #3 \\ #4 \end{array}\right]}\) \(\newcommand{\cfourvec}[4]{\left[\begin{array}{c}#1 \\ #2 \\ #3 \\ #4 \end{array}\right]}\) \(\newcommand{\fivevec}[5]{\left[\begin{array}{r}#1 \\ #2 \\ #3 \\ #4 \\ #5 \\ \end{array}\right]}\) \(\newcommand{\cfivevec}[5]{\left[\begin{array}{c}#1 \\ #2 \\ #3 \\ #4 \\ #5 \\ \end{array}\right]}\) \(\newcommand{\mattwo}[4]{\left[\begin{array}{rr}#1 \amp #2 \\ #3 \amp #4 \\ \end{array}\right]}\) \(\newcommand{\laspan}[1]{\text{Span}\{#1\}}\) \(\newcommand{\bcal}{\cal B}\) \(\newcommand{\ccal}{\cal C}\) \(\newcommand{\scal}{\cal S}\) \(\newcommand{\wcal}{\cal W}\) \(\newcommand{\ecal}{\cal E}\) \(\newcommand{\coords}[2]{\left\{#1\right\}_{#2}}\) \(\newcommand{\gray}[1]{\color{gray}{#1}}\) \(\newcommand{\lgray}[1]{\color{lightgray}{#1}}\) \(\newcommand{\rank}{\operatorname{rank}}\) \(\newcommand{\row}{\text{Row}}\) \(\newcommand{\col}{\text{Col}}\) \(\renewcommand{\row}{\text{Row}}\) \(\newcommand{\nul}{\text{Nul}}\) \(\newcommand{\var}{\text{Var}}\) \(\newcommand{\corr}{\text{corr}}\) \(\newcommand{\len}[1]{\left|#1\right|}\) \(\newcommand{\bbar}{\overline{\bvec}}\) \(\newcommand{\bhat}{\widehat{\bvec}}\) \(\newcommand{\bperp}{\bvec^\perp}\) \(\newcommand{\xhat}{\widehat{\xvec}}\) \(\newcommand{\vhat}{\widehat{\vvec}}\) \(\newcommand{\uhat}{\widehat{\uvec}}\) \(\newcommand{\what}{\widehat{\wvec}}\) \(\newcommand{\Sighat}{\widehat{\Sigma}}\) \(\newcommand{\lt}{<}\) \(\newcommand{\gt}{>}\) \(\newcommand{\amp}{&}\) \(\definecolor{fillinmathshade}{gray}{0.9}\)Multiple-Choice Problems
- Which of the following are structural isomers?
- Which of the following pairs are cis trans isomers?
- What is the name for an eight-carbon unbranched alkane chain?
- hexane
- heptane
- octane
- nonane
- decane
- Which of the following compounds are saturated hydrocarbons?
- Which of the following alkanes has the lowest boiling point?
- ethane
- propane
- butane
- pentane
- Which of the following has the highest energy?
- Which of the following is a cis isomer:
- Which of the following is the correct name for the following compound?
- 4-bromo-1,2-difluorobenzene
- 1,2-difluoro-3-bromobenzene
- 1,1-difluoro-2-bromobenzene
- 1-bromo-3-fluorobenzene
- Which of the following statements is false for the compound phenol?
- Phenol is a benzene derived compound.
- Phenol is highly toxic to the body even in small doses.
- Phenol can be used as a catalyst in the hydrogenation of benzene into cyclohexane.
- Phenol is used as an antiseptic in minute doses.
- In a reaction, compound L with the molecular formula C3H8O is converted to compound Z with the formula C3H6O. L is:
- oxidized
- reduced
- dehydrated
- none of these
- Which of the following would you expect to be soluble in water?
- CH3OCH3
- CH3CH2OH
- CH3CH2OCH 2CH2CH3
- CH3(CH2)3OH
Practice Problems
- Draw line structures from the following condensed structures.
- CH3CH2CH2OH
- CH3CH2CH2OCH(CH3)2
- CH3COCH2Cl
- CH3CO2CH2CH3
- (CH3CH2)3CCH=CH3
- Write molecular formulas for the following molecules.
- Sulfonilamide, an antibiotic
- Cholesterol
- Fluoxetine, an antidepressant
- Naproxen, an anti-inflammatory drug
- Diphenhydramine, an antihistamine
- Sulfonilamide, an antibiotic
- Identify the following functional groups in molecules from the previous problem: amine, carboxylic acid, ether, aromatic, alcohol, alkyl halide.
- Find mistakes in the following Lewis structures, then draw a correct related structure with the same molecular formula. If there are no problems with a given structure, write “correct”.
- Find mistakes in the following Lewis structures, then draw a correct related structure with the same molecular formula. If there are no problems with a given structure, write “correct”.
- Which of the following would you expect to be soluble in water?
- Vitamin C
- serotonin
- caffeine
- benzene
- Name the following acyclic hydrocarbons.
- CH4
- CH3CH3
- CH3CH2CH3
- CH3CH2CH2CH3
- Name the following compounds:
- Name three properties of hydrocarbons.
- What are the products of a combustion reaction?
- What is the monomer of PVC?
- Which of the following are aromatic compounds?
- Name the following compounds.
- Name the following compound using OMP nomenclature:
- What is the functional group of 1-propanol, CH3CH2CH2OH?
- What is the functional group of chlorobutane, CH3CH2CH2CH2Cl?
- Name each alcohol and classify them as primary, secondary, or tertiary.
- CH3CH2CH2CH2CH2OH
- Draw the structure for each of the following alcohols.
- 3-pentanol
- 2,2-dimethyl-3-butanol
- cyclopropanol
- 3-methyl-2-hexanol
- 3-ethyl-3,4-dimethyl-2-heptanol
- Why is methanol more soluble in water than 1-heptanol?
- Why does 1-propanol have a lower boiling point than 1-heptanol?
- Arrange these alcohols in order of increasing boiling point: 1-pentanol, methanol, and 1-hexanol.
- Draw the structure of glycerol, (HOCH2)2CHOH.
- Rank the following compounds in order of increasing boiling point:
- CH3OCH3
- CH3(CH2)2O(CH2)2CH3
- CH3(CH2)3OH
- CH3CH2OH
- Rank the following compounds in order of increasing boiling point:
- CH3CH2I
- CH3CH2Br
- CH3CH2Cl
- Rank the following compounds in order of increasing boiling point:
- CH3CH2I
- CH3CH3
- CH3CH2CH2I
- Circle all the chiral centers in ritonavir.
ritonavir
- Draw the ketone and aldehyde isomers of compounds containing the chemical formula of C3H6O.
- Name the following compounds.
- Name the following compounds.
- Which compound in each pair has the higher boiling point? Why?
- propanol and propanal
- propane and 2-propanone
- 2-propanone and 2-butanone