11.04: Characteristic Absoptions
- Page ID
- 20688
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\(\newcommand{\avec}{\mathbf a}\) \(\newcommand{\bvec}{\mathbf b}\) \(\newcommand{\cvec}{\mathbf c}\) \(\newcommand{\dvec}{\mathbf d}\) \(\newcommand{\dtil}{\widetilde{\mathbf d}}\) \(\newcommand{\evec}{\mathbf e}\) \(\newcommand{\fvec}{\mathbf f}\) \(\newcommand{\nvec}{\mathbf n}\) \(\newcommand{\pvec}{\mathbf p}\) \(\newcommand{\qvec}{\mathbf q}\) \(\newcommand{\svec}{\mathbf s}\) \(\newcommand{\tvec}{\mathbf t}\) \(\newcommand{\uvec}{\mathbf u}\) \(\newcommand{\vvec}{\mathbf v}\) \(\newcommand{\wvec}{\mathbf w}\) \(\newcommand{\xvec}{\mathbf x}\) \(\newcommand{\yvec}{\mathbf y}\) \(\newcommand{\zvec}{\mathbf z}\) \(\newcommand{\rvec}{\mathbf r}\) \(\newcommand{\mvec}{\mathbf m}\) \(\newcommand{\zerovec}{\mathbf 0}\) \(\newcommand{\onevec}{\mathbf 1}\) \(\newcommand{\real}{\mathbb R}\) \(\newcommand{\twovec}[2]{\left[\begin{array}{r}#1 \\ #2 \end{array}\right]}\) \(\newcommand{\ctwovec}[2]{\left[\begin{array}{c}#1 \\ #2 \end{array}\right]}\) \(\newcommand{\threevec}[3]{\left[\begin{array}{r}#1 \\ #2 \\ #3 \end{array}\right]}\) \(\newcommand{\cthreevec}[3]{\left[\begin{array}{c}#1 \\ #2 \\ #3 \end{array}\right]}\) \(\newcommand{\fourvec}[4]{\left[\begin{array}{r}#1 \\ #2 \\ #3 \\ #4 \end{array}\right]}\) \(\newcommand{\cfourvec}[4]{\left[\begin{array}{c}#1 \\ #2 \\ #3 \\ #4 \end{array}\right]}\) \(\newcommand{\fivevec}[5]{\left[\begin{array}{r}#1 \\ #2 \\ #3 \\ #4 \\ #5 \\ \end{array}\right]}\) \(\newcommand{\cfivevec}[5]{\left[\begin{array}{c}#1 \\ #2 \\ #3 \\ #4 \\ #5 \\ \end{array}\right]}\) \(\newcommand{\mattwo}[4]{\left[\begin{array}{rr}#1 \amp #2 \\ #3 \amp #4 \\ \end{array}\right]}\) \(\newcommand{\laspan}[1]{\text{Span}\{#1\}}\) \(\newcommand{\bcal}{\cal B}\) \(\newcommand{\ccal}{\cal C}\) \(\newcommand{\scal}{\cal S}\) \(\newcommand{\wcal}{\cal W}\) \(\newcommand{\ecal}{\cal E}\) \(\newcommand{\coords}[2]{\left\{#1\right\}_{#2}}\) \(\newcommand{\gray}[1]{\color{gray}{#1}}\) \(\newcommand{\lgray}[1]{\color{lightgray}{#1}}\) \(\newcommand{\rank}{\operatorname{rank}}\) \(\newcommand{\row}{\text{Row}}\) \(\newcommand{\col}{\text{Col}}\) \(\renewcommand{\row}{\text{Row}}\) \(\newcommand{\nul}{\text{Nul}}\) \(\newcommand{\var}{\text{Var}}\) \(\newcommand{\corr}{\text{corr}}\) \(\newcommand{\len}[1]{\left|#1\right|}\) \(\newcommand{\bbar}{\overline{\bvec}}\) \(\newcommand{\bhat}{\widehat{\bvec}}\) \(\newcommand{\bperp}{\bvec^\perp}\) \(\newcommand{\xhat}{\widehat{\xvec}}\) \(\newcommand{\vhat}{\widehat{\vvec}}\) \(\newcommand{\uhat}{\widehat{\uvec}}\) \(\newcommand{\what}{\widehat{\wvec}}\) \(\newcommand{\Sighat}{\widehat{\Sigma}}\) \(\newcommand{\lt}{<}\) \(\newcommand{\gt}{>}\) \(\newcommand{\amp}{&}\) \(\definecolor{fillinmathshade}{gray}{0.9}\) Bond type | Frequency (cm-1) |
C-H alkane | 2950 – 2850 |
C-H alkene | 3080 – 3020 |
C-H aldehyde | ~2900 |
C-H alkyne | ~3300 |
alkyne triple bond | 2250 – 2100 (s) |
alkene double bond | 1680 - 1620 (s) |
carbonyl, ketone | 1725 – 1700 (s) |
carbonyl, aldehyde | 1740 – 1720 (s) |
carbonyl, ester | 1750 – 1730 (s) |
carbonyl, acid | 1725 – 1700 (s) |
carbonyl, amide | 1690 – 1650 (s) |
O-H, alcohol | 3600 – 3200 (s, broad) |
O-H, acid | 3000 – 2500 (s, broad) |
C-O, alcohol, ester, ether | 1300 - 1000 |
s = strong absorbance
Callstack: at (Under_Construction/Purgatory/Book:_Organic_Chemistry_with_a_Biological_Emphasis_(Soderberg)/Reference_Tables/Some_characteristic_absorption_frequencies_in_IR_spectroscopy), /content/body/div/p/span, line 1, column 2 at wiki.page() at (Courses/Purdue/Purdue:_Chem_26200:_Organic_Chemistry_II_(Wenthold)/Chapter_11:__IR_and_Mass_Spectrometry/11.04:_Characteristic_Absoptions), /content/body/p/span, line 1, column 11
Contributors
- Organic Chemistry With a Biological Emphasis, Tim Soderberg (University of Minnesota, Morris)
Additional Reading
Michigan State Virtual Textbook of Organic Chemistry
Web Pages
Examples of IR bands for functional groups
Detailed list of peak positions
Detailed chart of IR Absorptions
Interpretation of IR spectra with examples
Tool for comparing IR spectra of two molecules
table of characteristic absorptions
Identifying alcohols and amines in IR
Detailed list of IR peak position
Identifying functional groups with IR
Why IR is important and identifying functional groups
Videos