4.13: Valence Electrons
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A chemical reaction involves either electron removal, electron addition, or electron sharing. The path that a specific element will take in a reaction depends on where the electrons are in the atom and how many there are.
In the study of chemical reactivity, electrons in the outermost principal energy level are very important and so are given a special name. Valence electrons are the electrons in the highest occupied principal energy level of an atom. In the second period elements, the two electrons in the 1s sublevel are called inner-shell electrons and are not involved directly in the element's reactivity, or in the formation of compounds. Lithium has a single electron in the second principal energy level, and so we say that lithium has one valence electron. Beryllium has two valence electrons. How many valence electrons does boron have? Recognize that the second principal energy level consists of both the 2s and the 2p sublevels, and so the answer is three. In fact, the number of valence electrons goes up by one for each step across a period, until the last element is reached. Neon, with its configuration ending in 2s22p6, has eight valence electrons.