Solutions 1
- Page ID
- 204072
Q1
Write out the complete time-independent Hamiltonians for (each term is explicitly given):
- the helium atom, electrons 1,2: \[ -\dfrac{\hbar^2}{2m_e}(\nabla^2_1 + \nabla^2_2) - \dfrac{Ze^2}{4\pi\epsilon}(\dfrac{1}{r_1}+\dfrac{1}{r_2}) + \dfrac{e^2}{4\pi\epsilon r_{12}}\]
- the \(H_2^+\) ion, nuclei A,B: \[ -\dfrac{\hbar^2}{2m_p}(\nabla^2_A + \nabla^2_B) - \dfrac{Ze^2}{4\pi\epsilon}(\dfrac{1}{r_A}+\dfrac{1}{r_B}) + \dfrac{e^2}{4\pi\epsilon r_{AB}}\]
- the \(H_2\) molecule, nuclei A,B electrons 1,2: \[ -\dfrac{\hbar^2}{2m_p}(\nabla^2_A + \nabla^2_B) -\dfrac{\hbar^2}{2m_e}(\nabla^2_1 + \nabla^2_2) - \dfrac{e^2}{4\pi\epsilon} (\dfrac{1}{r_{1A}}+\dfrac{1}{r_{1B}} + \dfrac{1}{r_{2A}}+\dfrac{1}{r_{2B}} -\dfrac{1}{r_{AB}} - \dfrac{1}{r_{12} })\]
Q2
What is the Born-Oppenheimer approximation and what do we use it for? When would it fail?
The Born-Oppenheimer approximation assumes that the nuclei in a system are stationary relative to the faster moving electrons. This allows separation of the wavefunction into a nuclear contribution and an independent electronic contribution. The approximation fails when nuclear motion is non-neglible (i.e., if the nuclei are moving faster than expected such as if very vibrational excited).
Q3
Confirm two s-p orbitals are orthonormal. The two \(|sp \rangle\) orbitals are:
\[ | sp_1 \rangle = \dfrac{1}{\sqrt {2}}( |2s\rangle + |2p \rangle)\]
\[ | sp_2 \rangle = \dfrac{1}{\sqrt {2}}( |2s\rangle - |2p \rangle)\]
Orthonormal means fulfilling both orthogonality and normality.
Normality means showing:
\[ \langle sp_1 | sp_1 \rangle = \langle sp_2 | sp_2 \rangle = 1\]
Orthogonality means showing:
\[ \langle sp_1 | sp_2 \rangle = \langle sp_2 | sp_1 \rangle = 0\]
We must keep in mind that s and p orbitals are orthonormal:
\[ \langle s|s \rangle = \langle p|p \rangle = 1 \]
and
\[ \langle s|p \rangle = \langle p|s \rangle = 0 \]
Therefore using the decomposition of the hybrid orbitals....
\[ \langle sp_1 | sp_1 \rangle = \dfrac{1}{\sqrt {2}}( \langle2s| + \langle2p |) \dfrac{1}{\sqrt {2}}( |2s\rangle + |2p \rangle) = \dfrac{1}{2}( \langle s|s \rangle + \langle s|p \rangle + \langle p|s \rangle + \langle p|p \rangle ) = \dfrac{1}{2}( 1 + 0 + 0 + 1) = 1 \]
\[ \langle sp_2 | sp_2 \rangle = \dfrac{1}{\sqrt {2}}( \langle2s| - \langle2p |) \dfrac{1}{\sqrt {2}}( |2s\rangle - |2p \rangle) = \dfrac{1}{2}( \langle s|s \rangle - \langle s|p \rangle - \langle p|s \rangle + \langle p|p \rangle ) = \dfrac{1}{2}( 1 - 0 - 0 + 1) = 1 \]
\[ \langle sp_1 | sp_2 \rangle = \dfrac{1}{\sqrt {2}}( \langle2s| + \langle2p |) \dfrac{1}{\sqrt {2}}( |2s\rangle - |2p \rangle) = \dfrac{1}{2}( \langle s|s \rangle - \langle s|p \rangle - \langle p|s \rangle - \langle p|p \rangle ) = \dfrac{1}{2}( 1 - 0 + 0 - 1) = 0 \]
\[ \langle sp_2 | sp_1 \rangle = \dfrac{1}{\sqrt {2}}( \langle2s| - \langle2p |) \dfrac{1}{\sqrt {2}}( |2s\rangle + |2p \rangle) = \dfrac{1}{2}( \langle s|s \rangle - \langle s|p \rangle - \langle p|s \rangle - \langle p|p \rangle ) = \dfrac{1}{2}( 1 + 0 - 0 - 1) = 0 \]
Q4
Show \(|sp^2\rangle = \dfrac{|s\rangle + \sqrt{2} |p \rangle}{\sqrt{3}}\) is normalized if \(|s \rangle\) and \(|p \rangle\) are normalized. This means showing that \( \langle sp^2|sp^2\rangle = 1 \):
\[ \langle sp^2|sp^2\rangle = (\dfrac{\langle s | + \sqrt{2} \langle p |}{\sqrt{3}} )( \dfrac{|s\rangle + \sqrt{2} |p \rangle}{\sqrt{3}}) = \dfrac{1}{3}(\langle s | s \rangle + \sqrt{2} \langle s|p \rangle = \sqrt{2} \langle p | s \rangle + 2 \langle p|p \rangle) = \dfrac{1}{3}(1 + 0 + 0 + 2) = 1\]
Q5
What is the average energy of a Hydrogen atom \(|sp^2 \rangle\) hybrid orbital if energy of \( |s \rangle \) is \(E_s \) and energy of \(|p \rangle \) is \( E_p \)?
We are given that \( \langle s| \hat{H} | s \rangle = E_s \) and \( \langle p| \hat{H} | p \rangle = E_p \).
It is also useful to realize that
\[ \langle s| \hat{H} | p \rangle = \langle p| \hat{H} | s \rangle = 0 \]
\[ E = \dfrac{ \langle sp^2| \hat{H} | sp^2 \rangle}{ \langle sp^2|sp^2 \rangle} = \left(\dfrac{\langle s | + \sqrt{2} \langle p |}{\sqrt{3}} \right) \hat{H} \left( \dfrac{|s\rangle + \sqrt{2} |p \rangle}{\sqrt{3}} \right) \]
\[= \dfrac{1}{3}( \langle s| \hat{H} | s \rangle + \sqrt{2}\langle s| \hat{H} | p \rangle + \sqrt{2}\langle p| \hat{H} | s \rangle + 2 \langle p| \hat{H} | p \rangle = \dfrac{1}{3}(E_s + 0 + 0 + 2 E_p) \]
= \[ \dfrac{1}{3}E_s + \dfrac{2}{3}E_p \]
Q6
When one s orbital and two p orbitals are used to generate hybrid orbitals, a total of three orbitals are generated.