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Chemistry LibreTexts

Glossary

  • Page ID
    279584
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    Glossary Entries
    Word(s) Definition Image Caption Link Source
    Adiabatic Process A thermodynamic process in which no heat is exchanged between a system and its surroundings.        
    Activity An effective concentration used in non-ideal solutions and gases to account for deviations from ideal behavior.        
    Avogadro’s Law States that equal volumes of gases at the same temperature and pressure contain an equal number of molecules.        
    Born-Haber Cycle A thermodynamic cycle used to calculate lattice energy in ionic solids.        
    Buffer A solution that resists changes in pH when small amounts of acid or base are added.        
    Calorimetry The measurement of heat flow in chemical reactions and physical changes.        
    Carnot Cycle A theoretical thermodynamic cycle that describes the most efficient heat engine possible.        
    Chemical Potential The change in a system’s Gibbs energy with the addition of a mole of a substance, at constant temperature and pressure.        
    Clapeyron Equation Describes the relationship between pressure, temperature, and phase equilibrium.        
    Colligative Properties Properties of solutions that depend on solute particle number rather than type, such as boiling point elevation.        
    Degree of Dissociation The fraction of a dissolved substance that separates into ions in solution.        
    Electrochemical Cell A system that generates electrical energy from chemical reactions.        
    Entropy A measure of disorder or randomness in a system.        
    Enthalpy The heat content of a system at constant pressure.        
    Equation of State A mathematical equation that describes the state of matter under given conditions, such as the ideal gas law.        
    Fugacity A corrected pressure term used to describe real gas behavior.        
    Free Energy, Gibbs Free Energy A thermodynamic quantity used to predict whether a reaction is spontaneous at constant pressure and temperature.        
    Gibbs-Duhem Equation Relates the chemical potentials of components in a mixture.        
    Graham’s Law of Effusion States that the rate of effusion of a gas is inversely proportional to the square root of its molar mass.        
    Half-Life The time required for half of a reactant to be consumed in a reaction.        
    Helmholtz Energy A thermodynamic function that measures the work potential of a system at constant volume and temperature.        
    Ideal Gas Law An equation describing the state of an ideal gas: PV=nRT.        
    Joule-Thomson Effect Describes the temperature change of a real gas when it is expanded or compressed without heat exchange.        
    Kinetic Molecular Theory A model that explains gas behavior based on particle motion and collisions.        
    Lattice Energy The energy required to separate an ionic solid into its gaseous ions.        
    Le Chatelier’s Principle States that a system at equilibrium will adjust to counteract applied changes.        
    Maxwell’s Relations A set of thermodynamic equations derived from the symmetry of second derivatives of thermodynamic potentials.        
    Michaelis-Menten Mechanism A model describing enzyme-catalyzed reactions.        
    Non-Ideal Solution A solution that deviates from Raoult’s law due to intermolecular interactions.        
    Partial Molar Volume The volume contribution of a component in a mixture.        
    Phase Diagram A graphical representation of phase stability as a function of temperature and pressure.        
    Pressure Dependence of Gibbs Energy Describes how Gibbs energy varies with pressure.        
    Raoult’s Law States that the vapor pressure of a solvent is proportional to its mole fraction in solution.        
    Reaction Mechanism A step-by-step description of how a chemical reaction occurs.        
    Reaction Rate The speed at which reactants are converted to products.        
    Solubility The ability of a substance to dissolve in a solvent.        
    Standard Reduction Potential A measure of the tendency of a chemical species to gain electrons.        
    Steady-State Approximation Assumes that the concentration of reaction intermediates remains constant over time.        
    Temperature Dependence of Equilibrium Constant Describes how equilibrium constants change with temperature.        
    Transition State Theory A model describing the high-energy transition state of a reaction.        
    Van ’t Hoff Equation Relates temperature changes to equilibrium constant changes.        
    Volume Dependence of Helmholtz Energy Explains how Helmholtz energy changes with volume variations.        
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