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5.7: Problems and Reference

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    Problems:

    Complete the following transformations.

    clipboard_e9f504f50cdec821dcf12c5b14bf60e76.png

    How will you prepare the following chiral ligands?

    clipboard_e93d8000bdccad05c56450d17070c8026.png

    Complete the following reactions.

    clipboard_e434f1d307358d9ff716293b60a35dd33.png

    Predict the major products for the following reactions.

    clipboard_eb60803d02c3ccd6d697f632d8d2c9a38.png

    List three effective organo catalysts for the epoxidation of α,β -unsaturated ketones. Provide mechanism.

    List three effective organo catalysts for the epoxidation of α,β -unsaturated aldehydes. Provide mechanism.

    Complete the following reactions.

    clipboard_e0106e1d29cf60bb647517f8a5a410a9c.png

    Describe chiral phosphoric acid catalyzed asymmetric Baeyer-Villiger oxidation.

    Complete the following reactions.

    clipboard_e0a6cd28a317ab0158092a679c7e33f15.png

    What product(s) would you expect from the following reactions?

    clipboard_e698a7f45a928044e0a4140e486c37a2a.png

    Reference/Text Book

    1. I. Ojima, Catalytic Asymmetric Synthesis , 3 rd ed., Wiley, New Jersey, 2010.

    2. M. B. Smith, Organic Synthesis , 2 nd edition, McGraw Hill, New Delhi, 2004.

    • Ojima, Catalytic Asymmetric Synthesis, VCH Publishers, Inc., New York 1993.

    This page titled 5.7: Problems and Reference is shared under a CC BY-SA license and was authored, remixed, and/or curated by Tharmalingam Punniyamurthy (National Programme on Technology Enhanced Learning (NPTEL) ) .

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