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  • https://chem.libretexts.org/Bookshelves/Inorganic_Chemistry/Supplemental_Modules_and_Websites_(Inorganic_Chemistry)/Molecular_Geometry/Trigonal_Bipyramidal_Molecular_Geometry
    AX 5 Shape: trigonal bipyramidal Steric Number: Lone Pairs: Polar/NonPolar: sp 3 d PCl 5 , SbF 5 NOTES: This molecule is made up of 5 sp 3 d hybrid orbitals. Three orbitals are arranged around the equ...AX 5 Shape: trigonal bipyramidal Steric Number: Lone Pairs: Polar/NonPolar: sp 3 d PCl 5 , SbF 5 NOTES: This molecule is made up of 5 sp 3 d hybrid orbitals. Three orbitals are arranged around the equator of the molecule with bond angles of 120 o . Two orbitals are arranged along the vertical axis at 90 o from the equatorial orbitals. The shape of the orbitals is trigonal bipyramidal. Since there is an atom at the end of each orbital, the shape of the molecule is also trigonal bipyramidal.
  • https://chem.libretexts.org/Bookshelves/Inorganic_Chemistry/Supplemental_Modules_and_Websites_(Inorganic_Chemistry)/Molecular_Geometry/Trigonal_Pyramidal_Molecular_Geometry
    Compare it to the water molecule which has 2 hydrogen atoms and 2 lone electron pairs.. The third hydrogen bonds to the water molecule as a hydrogen ion (no electrons) bonding to the lone pair on the ...Compare it to the water molecule which has 2 hydrogen atoms and 2 lone electron pairs.. The third hydrogen bonds to the water molecule as a hydrogen ion (no electrons) bonding to the lone pair on the oxygen. The sulfur and and one oxygen are bonded through a double bond which counts as "one electron pair". Hence the molecule has four electron pairs and is tetrahedral.
  • https://chem.libretexts.org/Bookshelves/Inorganic_Chemistry/Supplemental_Modules_and_Websites_(Inorganic_Chemistry)/Molecular_Geometry/Bent_Molecular_Geometry
    The molecule that is made up of 4 equally spaced sp3 hybrid orbitals forming bond angles of approximately 109.5o. The shape of the orbitals is tetrahedral. Two of the orbitals contain lone pairs of el...The molecule that is made up of 4 equally spaced sp3 hybrid orbitals forming bond angles of approximately 109.5o. The shape of the orbitals is tetrahedral. Two of the orbitals contain lone pairs of electrons. The two atoms connected to the central atom form a molecule with a bent shape.

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