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  • https://chem.libretexts.org/Courses/Lafayette_College/CHEM_440%3A_Structure_Determination/04%3A_X-ray_Crystallography/4.01%3A_Background
    The X-ray beams travel different pathlengths before hitting the various planes of the crystal, so after diffraction, the beams will interact constructively only if the path length difference is equal ...The X-ray beams travel different pathlengths before hitting the various planes of the crystal, so after diffraction, the beams will interact constructively only if the path length difference is equal to an integer number of wavelengths (just like in the normal diffraction case above).

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