The first law of thermodynamics states that the energy of the universe is constant. The change in the internal energy of a system is the sum of the heat transferred and the work done. At constant pres...The first law of thermodynamics states that the energy of the universe is constant. The change in the internal energy of a system is the sum of the heat transferred and the work done. At constant pressure, heat flow (q) and internal energy (U) are related to the system’s enthalpy (H). The heat flow is equal to the change in the internal energy.