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  • https://chem.libretexts.org/Courses/BridgeValley_Community_and_Technical_College/Consumer_Chemistry/09%3A_Biochemistry/9.01%3A_Carbohydrates_Fundamentals/9.1.03%3A_Carbohydrate_Isomers
    With the aldehyde group in the "up" direction, the the -OH group must project to the right side of the molecule for the D isomer. It is remarkable that the chemistry and enzymes of all living things c...With the aldehyde group in the "up" direction, the the -OH group must project to the right side of the molecule for the D isomer. It is remarkable that the chemistry and enzymes of all living things can tell the difference between the geometry of one optical isomer over the other. Monosaccharides are assigned to the D-family according to the projection of the -OH group to the right on the chiral carbon that is the farthest from the carbonyl (aldehyde) group.
  • https://chem.libretexts.org/Workbench/Chemistry_LHS_Bridge/17%3A_Carbohydrates/17.01%3A_Carbohydrates_Fundamentals/17.1.02%3A_Carbohydrate_Isomers
    With the aldehyde group in the "up" direction, the the -OH group must project to the right side of the molecule for the D isomer. It is remarkable that the chemistry and enzymes of all living things c...With the aldehyde group in the "up" direction, the the -OH group must project to the right side of the molecule for the D isomer. It is remarkable that the chemistry and enzymes of all living things can tell the difference between the geometry of one optical isomer over the other. Monosaccharides are assigned to the D-family according to the projection of the -OH group to the right on the chiral carbon that is the farthest from the carbonyl (aldehyde) group.

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