To standardize an analytical method we also must determine the value of \(k_A\) . In principle, it should be possible to derive the value of \(k_A\) for any analytical method by considering the chemi...To standardize an analytical method we also must determine the value of \(k_A\) . In principle, it should be possible to derive the value of \(k_A\) for any analytical method by considering the chemical and physical processes generating the signal. Unfortunately, such calculations are not feasible when we lack a sufficiently developed theoretical model of the physical processes, or are not useful because of nonideal chemical behavior.
To standardize an analytical method we also must determine the value of \(k_A\) . In principle, it should be possible to derive the value of \(k_A\) for any analytical method by considering the chemi...To standardize an analytical method we also must determine the value of \(k_A\) . In principle, it should be possible to derive the value of \(k_A\) for any analytical method by considering the chemical and physical processes generating the signal. Unfortunately, such calculations are not feasible when we lack a sufficiently developed theoretical model of the physical processes, or are not useful because of nonideal chemical behavior.