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  • https://chem.libretexts.org/Courses/Lakehead_University/Analytical_I/5%3A_Standardizing_Analytical_Methods/5.3%3A_Determining_the_Sensitivity
    To standardize an analytical method we also must determine the value of \(k_A\) .  In principle, it should be possible to derive the value of \(k_A\) for any analytical method by considering the chemi...To standardize an analytical method we also must determine the value of \(k_A\) .  In principle, it should be possible to derive the value of \(k_A\) for any analytical method by considering the chemical and physical processes generating the signal. Unfortunately, such calculations are not feasible when we lack a sufficiently developed theoretical model of the physical processes, or are not useful because of nonideal chemical behavior.
  • https://chem.libretexts.org/Courses/Los_Angeles_Trade_Technical_College/Analytical_Chemistry/2%3A_Analytical_Chemistry_2.0_(Harvey)/06%3A_Standardizing_Analytical_Methods/6.3%3A_Determining_the_Sensitivity
    To standardize an analytical method we also must determine the value of \(k_A\) .  In principle, it should be possible to derive the value of \(k_A\) for any analytical method by considering the chemi...To standardize an analytical method we also must determine the value of \(k_A\) .  In principle, it should be possible to derive the value of \(k_A\) for any analytical method by considering the chemical and physical processes generating the signal. Unfortunately, such calculations are not feasible when we lack a sufficiently developed theoretical model of the physical processes, or are not useful because of nonideal chemical behavior.

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