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- https://chem.libretexts.org/Courses/East_Tennessee_State_University/CHEM_3110%3A_Descriptive_Inorganic_Chemistry/11%3A_Organometallic_ChemistryMetals cover a vast swath of the periodic table and include the alkali metals, alkali earth metals, transition metals, the main group metals, and the lanthanides and actinides. There’s a reason the “o...Metals cover a vast swath of the periodic table and include the alkali metals, alkali earth metals, transition metals, the main group metals, and the lanthanides and actinides. There’s a reason the “organo” comes first in “organometallic chemistry”—These catalysts usually the aid in the creation of new bonds in organic compounds, building up complex products from simple starting materials.
- https://chem.libretexts.org/Bookshelves/Organic_Chemistry/Organic_Chemistry_(OpenStax)/08%3A_Alkenes_-_Reactions_and_Synthesis/8.05%3A_Hydration_of_Alkenes_-_Addition_of_HO_by_HydroborationIn addition to the oxymercuration–demercuration method, which yields the Markovnikov product, a complementary method that yields the non-Markovnikov product is also useful. Discovered in 1959 by H.C. ...In addition to the oxymercuration–demercuration method, which yields the Markovnikov product, a complementary method that yields the non-Markovnikov product is also useful. Discovered in 1959 by H.C. Brown at Purdue University and called hydroboration, the reaction involves addition of a B−H bond of borane to an alkene to yield an organoborane intermediate. Oxidation of the organoborane by reaction with basic hydrogen peroxide, then gives an alcohol.
- https://chem.libretexts.org/Bookshelves/Organic_Chemistry/Organic_Chemistry_(Morsch_et_al.)/08%3A_Alkenes-_Reactions_and_Synthesis/8.05%3A_Hydration_of_Alkenes_-_Addition_of_HO_by_HydroborationHydroboration-oxidation is a two step pathway used to produce alcohols. The reaction proceeds in an anti-Markovnikov manner, where the hydrogen (from BH3 or BHR2) attaches to the more substituted carb...Hydroboration-oxidation is a two step pathway used to produce alcohols. The reaction proceeds in an anti-Markovnikov manner, where the hydrogen (from BH3 or BHR2) attaches to the more substituted carbon and the boron attaches to the least substituted carbon in the alkene double bond. Furthermore, the borane acts as a Lewis acid by accepting two electrons in its empty p orbital from an alkene that is electron rich.
- https://chem.libretexts.org/Courses/Kutztown_University_of_Pennsylvania/CHM_320%3A_Advanced_Inorganic_Chemistry_textbook/13%3A_Introduction_to_Organometallic_Complexes/13.01%3A_What_is_Organometallic_ChemistryThe goal of this otherwise content-free post is twofold: (1) to help motivate us as we move forward (that is, to constantly remind us that there is a point to all this!); and (2) to illustrate the kin...The goal of this otherwise content-free post is twofold: (1) to help motivate us as we move forward (that is, to constantly remind us that there is a point to all this!); and (2) to illustrate the kinds of problems we’ll be able to address using concepts from the field.
- https://chem.libretexts.org/Courses/Centre_College/CHE_332%3A_Inorganic_Chemistry/10%3A_Organometallic_ChemistryMetals cover a vast swath of the periodic table and include the alkali metals, alkali earth metals, transition metals, the main group metals, and the lanthanides and actinides. There’s a reason the “o...Metals cover a vast swath of the periodic table and include the alkali metals, alkali earth metals, transition metals, the main group metals, and the lanthanides and actinides. There’s a reason the “organo” comes first in “organometallic chemistry”—These catalysts usually the aid in the creation of new bonds in organic compounds, building up complex products from simple starting materials.
- https://chem.libretexts.org/Bookshelves/Organic_Chemistry/Basic_Principles_of_Organic_Chemistry_(Roberts_and_Caserio)/11%3A_Alkenes_and_Alkynes_II_-_Oxidation_and_Reduction_Reactions._Acidity_of_Alkynes/11.06%3A_Addition_of_Boron_Hydrides_to_Alkenes._OrganoboranesHydroboration and the many uses of organoboranes in synthesis were developed largely by H. C. Brown and co-workers. In our discussion, we shall give more detail on hydroboration itself, and then descr...Hydroboration and the many uses of organoboranes in synthesis were developed largely by H. C. Brown and co-workers. In our discussion, we shall give more detail on hydroboration itself, and then describe several useful transformations of organoboranes.
- https://chem.libretexts.org/Courses/Saint_Marys_College_Notre_Dame_IN/CHEM_431%3A_Inorganic_Chemistry_(Haas)/CHEM_431_Readings/18%3A_Introduction_to_Organometallic_Complexes/18.01%3A_What_is_Organometallic_ChemistryThe goal of this otherwise content-free post is twofold: (1) to help motivate us as we move forward (that is, to constantly remind us that there is a point to all this!); and (2) to illustrate the kin...The goal of this otherwise content-free post is twofold: (1) to help motivate us as we move forward (that is, to constantly remind us that there is a point to all this!); and (2) to illustrate the kinds of problems we’ll be able to address using concepts from the field.
- https://chem.libretexts.org/Courses/Westminster_College/CHE_261_-_Organic_Chemistry_I/09%3A_Electrophilic_Addition_Reactions_of_Alkenes_and_Alkynes/9.09%3A_Addition_of_Boron_Hydrides_to_Alkenes._OrganoboranesHydroboration and the many uses of organoboranes in synthesis were developed largely by H. C. Brown and co-workers. In our discussion, we shall give more detail on hydroboration itself, and then descr...Hydroboration and the many uses of organoboranes in synthesis were developed largely by H. C. Brown and co-workers. In our discussion, we shall give more detail on hydroboration itself, and then describe several useful transformations of organoboranes.
- https://chem.libretexts.org/Bookshelves/Inorganic_Chemistry/Organometallic_Chemistry_(Evans)/01%3A_Introduction_to_Organometallic_Chemistry/1.02%3A_What_is_Organometallic_ChemistryThe goal of this otherwise content-free post is twofold: (1) to help motivate us as we move forward (that is, to constantly remind us that there is a point to all this!); and (2) to illustrate the kin...The goal of this otherwise content-free post is twofold: (1) to help motivate us as we move forward (that is, to constantly remind us that there is a point to all this!); and (2) to illustrate the kinds of problems we’ll be able to address using concepts from the field.
