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  • https://chem.libretexts.org/Bookshelves/General_Chemistry/Map%3A_Principles_of_Modern_Chemistry_(Oxtoby_et_al.)/Unit_6%3A_Materials/21%3A_Structure_and_Bonding_in_Solids/21.4%3A_Defects_and_Amorphous_Solids
    Few, if any, crystals are perfect in that all unit cells consist of the ideal arrangement of atoms or molecules and all cells line up in a three dimensional space with no distortion. Some cells may ha...Few, if any, crystals are perfect in that all unit cells consist of the ideal arrangement of atoms or molecules and all cells line up in a three dimensional space with no distortion. Some cells may have one or more atoms less whereas others may have one or more atoms than the ideal unit cell. The imperfection of crystals are called crystal defects. Crystal defects are results of thermodynamic equilibrium contributed also by the increase in entropy TS term of the Gibb's free energy.

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