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- https://chem.libretexts.org/Courses/Centre_College/CHE_332%3A_Inorganic_Chemistry/10%3A_Organometallic_Chemistry/10.02%3A_Organometallic_LigandsThere are some classes of ligands and modes of bonding that are important and in some cases unique to organometallic complexes and reactions. Before discussing reactions of organometallic complexes we...There are some classes of ligands and modes of bonding that are important and in some cases unique to organometallic complexes and reactions. Before discussing reactions of organometallic complexes we will start with an overview of ligands common to organometallic complexes. In organometallic reactions, ligands can be either spectators, not chemically involved or changed during the reaction, or actors, chemically changed during the reaction.
- https://chem.libretexts.org/Bookshelves/Inorganic_Chemistry/Inorganic_Chemistry_(LibreTexts)/13%3A_Organometallic_Chemistry/13.05%3A_Bonding_between_Metal_Atoms_and_Organic_Pi_Systems/13.5.03%3A_Odd-numbered__SystemsOdd-numbered π systems—most notably, the allyl and cyclopentadienyl ligands—are formally LnX-type ligands bound covalently through one atom (the “odd man out”) and datively through the others. This fo...Odd-numbered π systems—most notably, the allyl and cyclopentadienyl ligands—are formally LnX-type ligands bound covalently through one atom (the “odd man out”) and datively through the others. This formal description is incomplete, however, as resonance structures reveal that multiple atoms within three- and five-atom π systems can be considered as covalently bound to the metal.
- https://chem.libretexts.org/Courses/Ursinus_College/CHEM322%3A_Inorganic_Chemistry/10%3A_Organometallic_Chemistry/10.01%3A_Organometallic_Complexes/10.1.03%3A_Survey_of_Common_Organometallic_LigandsThere are some classes of ligands and modes of bonding that are important and in some cases unique to organometallic complexes and reactions. Before discussing reactions of organometallic complexes we...There are some classes of ligands and modes of bonding that are important and in some cases unique to organometallic complexes and reactions. Before discussing reactions of organometallic complexes we will start with an overview of ligands common to organometallic complexes. In organometallic reactions, ligands can be either spectators, not chemically involved or changed during the reaction, or actors, chemically changed during the reaction.
- https://chem.libretexts.org/Courses/Ripon_College/CHM_321%3A_Inorganic_Chemistry/06%3A_Organometallic_Chemistry/6.05%3A_Bonding_between_Metal_Atoms_and_Organic_Pi_Systems/6.5.03%3A_Odd-numbered__SystemsOdd-numbered π systems—most notably, the allyl and cyclopentadienyl ligands—are formally LnX-type ligands bound covalently through one atom (the “odd man out”) and datively through the others. This fo...Odd-numbered π systems—most notably, the allyl and cyclopentadienyl ligands—are formally LnX-type ligands bound covalently through one atom (the “odd man out”) and datively through the others. This formal description is incomplete, however, as resonance structures reveal that multiple atoms within three- and five-atom π systems can be considered as covalently bound to the metal.
- https://chem.libretexts.org/Courses/Saint_Marys_College_Notre_Dame_IN/CHEM_431%3A_Inorganic_Chemistry_(Haas)/CHEM_431_Readings/19%3A_Organometallic_Bonding_(Epic_Ligand_Survey)/19.09%3A_Odd-numbered__SystemsOdd-numbered π systems—most notably, the allyl and cyclopentadienyl ligands—are formally LnX-type ligands bound covalently through one atom (the “odd man out”) and datively through the others. This fo...Odd-numbered π systems—most notably, the allyl and cyclopentadienyl ligands—are formally LnX-type ligands bound covalently through one atom (the “odd man out”) and datively through the others. This formal description is incomplete, however, as resonance structures reveal that multiple atoms within three- and five-atom π systems can be considered as covalently bound to the metal.
- https://chem.libretexts.org/Courses/East_Tennessee_State_University/CHEM_3110%3A_Descriptive_Inorganic_Chemistry/11%3A_Organometallic_Chemistry/11.01%3A_Organometallic_LigandsThere are some classes of ligands and modes of bonding that are important and in some cases unique to organometallic complexes and reactions. Before discussing reactions of organometallic complexes we...There are some classes of ligands and modes of bonding that are important and in some cases unique to organometallic complexes and reactions. Before discussing reactions of organometallic complexes we will start with an overview of ligands common to organometallic complexes. In organometallic reactions, ligands can be either spectators, not chemically involved or changed during the reaction, or actors, chemically changed during the reaction.
- https://chem.libretexts.org/Bookshelves/Inorganic_Chemistry/Organometallic_Chemistry_(Evans)/02%3A_Organometallic_Ligands/2.08%3A_Odd-numbered__SystemsOdd-numbered π systems—most notably, the allyl and cyclopentadienyl ligands—are formally LnX-type ligands bound covalently through one atom (the “odd man out”) and datively through the others. This fo...Odd-numbered π systems—most notably, the allyl and cyclopentadienyl ligands—are formally LnX-type ligands bound covalently through one atom (the “odd man out”) and datively through the others. This formal description is incomplete, however, as resonance structures reveal that multiple atoms within three- and five-atom π systems can be considered as covalently bound to the metal.
- https://chem.libretexts.org/Courses/Tennessee_State_University/CHEM_4210%3A_Inorganic_Chem_II_(Siddiquee)/06%3A_Catalysis/6.05%3A_Bonding_between_Metal_Atoms_and_Organic_Pi_Systems/6.5.03%3A_Odd-numbered__SystemsOdd-numbered π systems—most notably, the allyl and cyclopentadienyl ligands—are formally LnX-type ligands bound covalently through one atom (the “odd man out”) and datively through the others. This fo...Odd-numbered π systems—most notably, the allyl and cyclopentadienyl ligands—are formally LnX-type ligands bound covalently through one atom (the “odd man out”) and datively through the others. This formal description is incomplete, however, as resonance structures reveal that multiple atoms within three- and five-atom π systems can be considered as covalently bound to the metal.
- https://chem.libretexts.org/Courses/East_Tennessee_State_University/CHEM_4110%3A_Advanced_Inorganic_Chemistry/10%3A_Organometallic_Chemistry/10.02%3A_Nomenclature_Ligands_and_Classification/10.2.02%3A_Bonding_between_Metal_Atoms_and_Organic_Pi_Systems/10.2.2.03%3A_Odd-numbered__SystemsOdd-numbered π systems—most notably, the allyl and cyclopentadienyl ligands—are formally LnX-type ligands bound covalently through one atom (the “odd man out”) and datively through the others. This fo...Odd-numbered π systems—most notably, the allyl and cyclopentadienyl ligands—are formally LnX-type ligands bound covalently through one atom (the “odd man out”) and datively through the others. This formal description is incomplete, however, as resonance structures reveal that multiple atoms within three- and five-atom π systems can be considered as covalently bound to the metal.
