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- https://chem.libretexts.org/Bookshelves/Organic_Chemistry/Organic_Synthesis_(Shea)/04%3A_Radical_ReactionsThis chapter focuses on radical reactions promoted by tributyltin hydride, like the Barton-McCombie deoxygenation and carbon-carbon bond forming radical chain reactions. It also covers non-chain radic...This chapter focuses on radical reactions promoted by tributyltin hydride, like the Barton-McCombie deoxygenation and carbon-carbon bond forming radical chain reactions. It also covers non-chain radical reactions that produce carbon-carbon bonds like the pinacol, McMurry, and Hoffmann-Loeffler-Freytag reactions.
- https://chem.libretexts.org/Bookshelves/Organic_Chemistry/Organic_Synthesis_(Shea)This text is designed to build on traditional Organic Chemistry I and II courses for an Advanced Organic Chemistry class. The focus is on key reaction types that enable the construction of complex org...This text is designed to build on traditional Organic Chemistry I and II courses for an Advanced Organic Chemistry class. The focus is on key reaction types that enable the construction of complex organic molecules: pericyclic reactions, transition metal catalyzed reactions, rearrangements, fragmentations, radical reactions, and carbene reactions. It explores these reactions through both mechanism and synthesis problems with many examples from the current literature.
- https://chem.libretexts.org/Bookshelves/Organic_Chemistry/Organic_Synthesis_(Shea)/01%3A_Pericyclic_Reactions/1.02%3A_Cycloaddition_ReactionsThis page covers common cycloaddition reactions, including the Diels-Alder reaction, ene reaction, photo [2+2], ketene [2+2], and 1,3-dipolar cycloadditions, and discusses why some are promoted by hea...This page covers common cycloaddition reactions, including the Diels-Alder reaction, ene reaction, photo [2+2], ketene [2+2], and 1,3-dipolar cycloadditions, and discusses why some are promoted by heat and others by light.
