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- https://chem.libretexts.org/Bookshelves/Inorganic_Chemistry/Inorganic_Chemistry_(LibreTexts)/13%3A_Organometallic_Chemistry/13.05%3A_Bonding_between_Metal_Atoms_and_Organic_Pi_Systems/13.5.03%3A_Odd-numbered__SystemsOdd-numbered π systems—most notably, the allyl and cyclopentadienyl ligands—are formally LnX-type ligands bound covalently through one atom (the “odd man out”) and datively through the others. This fo...Odd-numbered π systems—most notably, the allyl and cyclopentadienyl ligands—are formally LnX-type ligands bound covalently through one atom (the “odd man out”) and datively through the others. This formal description is incomplete, however, as resonance structures reveal that multiple atoms within three- and five-atom π systems can be considered as covalently bound to the metal.
- https://chem.libretexts.org/Courses/Ripon_College/CHM_321%3A_Inorganic_Chemistry/06%3A_Organometallic_Chemistry/6.05%3A_Bonding_between_Metal_Atoms_and_Organic_Pi_Systems/6.5.03%3A_Odd-numbered__SystemsOdd-numbered π systems—most notably, the allyl and cyclopentadienyl ligands—are formally LnX-type ligands bound covalently through one atom (the “odd man out”) and datively through the others. This fo...Odd-numbered π systems—most notably, the allyl and cyclopentadienyl ligands—are formally LnX-type ligands bound covalently through one atom (the “odd man out”) and datively through the others. This formal description is incomplete, however, as resonance structures reveal that multiple atoms within three- and five-atom π systems can be considered as covalently bound to the metal.
- https://chem.libretexts.org/Courses/Saint_Marys_College_Notre_Dame_IN/CHEM_431%3A_Inorganic_Chemistry_(Haas)/CHEM_431_Readings/19%3A_Organometallic_Bonding_(Epic_Ligand_Survey)/19.09%3A_Odd-numbered__SystemsOdd-numbered π systems—most notably, the allyl and cyclopentadienyl ligands—are formally LnX-type ligands bound covalently through one atom (the “odd man out”) and datively through the others. This fo...Odd-numbered π systems—most notably, the allyl and cyclopentadienyl ligands—are formally LnX-type ligands bound covalently through one atom (the “odd man out”) and datively through the others. This formal description is incomplete, however, as resonance structures reveal that multiple atoms within three- and five-atom π systems can be considered as covalently bound to the metal.
- https://chem.libretexts.org/Bookshelves/Inorganic_Chemistry/Organometallic_Chemistry_(Evans)/02%3A_Organometallic_Ligands/2.08%3A_Odd-numbered__SystemsOdd-numbered π systems—most notably, the allyl and cyclopentadienyl ligands—are formally LnX-type ligands bound covalently through one atom (the “odd man out”) and datively through the others. This fo...Odd-numbered π systems—most notably, the allyl and cyclopentadienyl ligands—are formally LnX-type ligands bound covalently through one atom (the “odd man out”) and datively through the others. This formal description is incomplete, however, as resonance structures reveal that multiple atoms within three- and five-atom π systems can be considered as covalently bound to the metal.
- https://chem.libretexts.org/Courses/Tennessee_State_University/CHEM_4210%3A_Inorganic_Chem_II_(Siddiquee)/06%3A_Catalysis/6.05%3A_Bonding_between_Metal_Atoms_and_Organic_Pi_Systems/6.5.03%3A_Odd-numbered__SystemsOdd-numbered π systems—most notably, the allyl and cyclopentadienyl ligands—are formally LnX-type ligands bound covalently through one atom (the “odd man out”) and datively through the others. This fo...Odd-numbered π systems—most notably, the allyl and cyclopentadienyl ligands—are formally LnX-type ligands bound covalently through one atom (the “odd man out”) and datively through the others. This formal description is incomplete, however, as resonance structures reveal that multiple atoms within three- and five-atom π systems can be considered as covalently bound to the metal.
- https://chem.libretexts.org/Courses/East_Tennessee_State_University/CHEM_4110%3A_Advanced_Inorganic_Chemistry/10%3A_Organometallic_Chemistry/10.02%3A_Nomenclature_Ligands_and_Classification/10.2.02%3A_Bonding_between_Metal_Atoms_and_Organic_Pi_Systems/10.2.2.03%3A_Odd-numbered__SystemsOdd-numbered π systems—most notably, the allyl and cyclopentadienyl ligands—are formally LnX-type ligands bound covalently through one atom (the “odd man out”) and datively through the others. This fo...Odd-numbered π systems—most notably, the allyl and cyclopentadienyl ligands—are formally LnX-type ligands bound covalently through one atom (the “odd man out”) and datively through the others. This formal description is incomplete, however, as resonance structures reveal that multiple atoms within three- and five-atom π systems can be considered as covalently bound to the metal.
