# 4.7: Organic Chemistry


##### Learning Objectives
• Define organic chemistry.
• Identify organic molecules as alkanes, alkenes, alkynes, alcohols, or carboxylic acids.

When methane was mentioned previously, we described it as the simplest organic compound. In this section, we introduce organic chemistry more formally. Organic chemistry is the study of the chemistry of carbon compounds. Carbon is singled out because it has a chemical diversity unrivaled by any other chemical element. Its diversity is based on the following:

• Carbon atoms bond reasonably strongly with other carbon atoms.
• Carbon atoms bond reasonably strongly with atoms of other elements.
• Carbon atoms make a large number of covalent bonds (four).

Curiously, elemental carbon is not particularly abundant. It does not even appear in the list of the most common elements in Earth’s crust. Nevertheless, all living things consist of organic compounds. Most organic chemicals are covalent compounds, which is why we introduce organic chemistry here. By convention, compounds containing carbonate ions and bicarbonate ions, as well as carbon dioxide and carbon monoxide, are not considered part of organic chemistry, even though they contain carbon.

### Alkanes

The simplest organic compounds are the hydrocarbons, compounds composed of carbon and hydrogen atoms only. Some hydrocarbons have only single bonds and appear as a chain (which can be a straight chain or can have branches) of carbon atoms also bonded to hydrogen atoms. These hydrocarbons are called alkanes (saturated hydrocarbons). Each alkane has a characteristic, systematic name depending on the number of carbon atoms in the molecule. These names consist of a stem that indicates the number of carbon atoms in the chain plus the ending -ane. The stem meth- means one carbon atom, so methane is an alkane with one carbon atom. Similarly, the stem eth- means two carbon atoms; ethane is an alkane with two carbon atoms. Continuing, the stem prop- means three carbon atoms, so propane is an alkane with three carbon atoms. The stem but- means four carbon atoms; butane is an alkane with four carbon atoms. Figure $$\PageIndex{1}$$ gives the Lewis structures, condensed structural formulas and molecular formulas of the four simplest alkanes. In the condensed structural formula, the covalent bonds are understood to exist between each carbon and the hydrogens associated with it, as well as between carbon atoms.

### Alkenes

Some hydrocarbons have one or more carbon–carbon double bonds (denoted C=C). These hydrocarbons are called alkenes. Figure $$\PageIndex{2}$$ shows the formulas and the molecular models of the two simplest alkenes. Note that the names of alkenes have the same stem as the alkane with the same number of carbon atoms in its chain but have the ending -ene. Thus, ethene is an alkene with two carbon atoms per molecule, and propene is a compound with three carbon atoms and one double bond.

### Alkynes

Alkynes are hydrocarbons with a carbon–carbon triple bond (denoted C≡C) as part of their carbon skeleton. Below is the formula and the molecular model of the simplest alkyne and its systematic name. Its common name is acetylene. Its chemical formula is C2H2.

Ethyne

The names for alkynes have the same stems as for alkanes but with the ending -yne.

##### To Your Health: Saturated and Unsaturated Fats

Hydrocarbons are not the only compounds that can have carbon–carbon double bonds. A group of compounds called fats can have them as well, and their presence or absence in the human diet is becoming increasingly correlated with health issues.

Fats are combinations of long-chain organic compounds (fatty acids) and glycerol (C3H8O3). (For more information on fats, see Chapter 17) The long carbon chains can have either all single bonds, in which case the fat is classified as saturated, or one or more double bonds, in which case it is a monounsaturated or a polyunsaturated fat, respectively. Saturated fats are typically solids at room temperature; beef fat (tallow) is one example. Mono- or polyunsaturated fats are likely to be liquids at room temperature and are often called oils. Olive oil, flaxseed oil, and many fish oils are mono- or polyunsaturated fats.

Studies have linked higher amounts of saturated fats in people’s diets with a greater likelihood of developing heart disease, high cholesterol, and other diet-related diseases. In contrast, increases in unsaturated fats (either mono- or polyunsaturated) have been linked to a lower incidence of certain diseases. Thus, there have been an increasing number of recommendations by government bodies and health associations to decrease the proportion of saturated fat and increase the proportion of unsaturated fat in the diet. Most of these organizations also recommend decreasing the total amount of fat in the diet.

Recently, certain fats called trans fats have been implicated in the presence of heart disease. These are fats from animal sources and are also produced when liquid oils are exposed to partial hydrogenation, an industrial process that increases their saturation. Trans fats are used in many prepared and fried foods. Because they bring with them the health risks that naturally occurring saturated fats do, there has been some effort to better quantify the presence of trans fats in food products. US law now requires that food labels list the amount of trans fat in each serving.

Since the early 1900's, the US Department of Agriculture has been providing science-based dietary guidelines for the public. The most current version is the MyPlate illustration that gives a simple, visual picture of how much of what kind of foods make up a good, balanced diet. It recommends minimizing daily intake of sugars, the "bad fats", trans and saturated fat, and sodium. "Good fats", unsaturated fats or oils, are not considered a food group but do contain essential nutrients and therefore are included as part of a healthy eating pattern. The difference as simple as the difference between a single and double carbon–carbon bond, good and bad fats, can have a significant impact on health.

### Functional Groups

The carbon–carbon double and triple bonds are examples of functional groups in organic chemistry. A functional group is a specific structural arrangement of atoms or bonds that imparts a characteristic chemical reactivity to a molecule. Alkanes have no functional group. A carbon–carbon double bond is considered a functional group because carbon–carbon double bonds chemically react in specific ways that differ from reactions of alkanes (for example, under certain circumstances, alkenes react with water); a carbon–carbon triple bond also undergoes certain specific chemical reactions. In the remainder of this section, we introduce two other common functional groups.

If an OH group (also called a hydroxyl group) is substituted for a hydrogen atom in a hydrocarbon molecule, the compound is an alcohol. Alcohols are named using the parent hydrocarbon name but with the final -e dropped and the suffix -ol attached. The two simplest alcohols are methanol and ethanol. Figure $$\PageIndex{4}$$ shows their formulas along with a molecular model of each.

Cholesterol, described in the chapter-opening essay, has an alcohol functional group, as its name implies.

##### Alcohol

Ethanol (also called ethyl alcohol) is the alcohol in alcoholic beverages. Other alcohols include methanol (or methyl alcohol), which is used as a solvent and a cleaner, and isopropyl alcohol (or rubbing alcohol), which is used as a medicinal disinfectant. Neither methanol nor isopropyl alcohol should be ingested, as they are toxic even in small quantities.

Another important family of organic compounds has a carboxyl group, in which a carbon atom is double-bonded to an oxygen atom and to an OH group. Compounds with a carboxyl functional group are called carboxylic acids, and their names end in -oic acid. Figure $$\PageIndex{5}$$ shows the formulas and the molecular models of the two simplest carboxylic acids, perhaps best known by the common names formic acid and acetic acid. The carboxyl group is sometimes written in molecules as COOH.

The condensed structures of methanoic acid and ethanoic acid are HCOOH and CH3COOH, respectively.

Many organic compounds are considerably more complex than the examples described here. Many compounds, such as cholesterol discussed in the chapter-opening essay, contain more than one functional group. The formal names can also be quite complex.

##### Example $$\PageIndex{1}$$

Identify the functional group(s) in each molecule as a double bond, a triple bond, an alcohol, or a carboxyl.

b.

c.

d. $$\ce{CH3CH2CH2CH2OH}$$

This molecule has a double bond and a carboxyl functional group.

This molecule has an alcohol functional group.

This molecule has a carbon-carbon double bond and a carboxyl functional group.

This molecule has an alcohol functional group.

##### Exercise $$\PageIndex{1}$$

Identify the functional group(s) in each molecule as a double bond, a triple bond, an alcohol, or a carboxyl.

d.

triple bond (alkyne)

carboxyl group

alcohol group

double bond (alkene) and carboxyl group

##### Career Focus: Forensic Chemist

The main job of a forensic chemist is to identify unknown materials and their origins. Although forensic chemists are most closely associated in the public mind with crime labs, they are employed in pursuits as diverse as tracing evolutionary patterns in living organisms, identifying environmental contaminants, and determining the origin of manufactured chemicals.

In a crime lab, the forensic chemist has the job of identifying the evidence so that a crime can be solved. The unknown samples may consist of almost anything—for example, paint chips, blood, glass, cloth fibers, drugs, or human remains. The forensic chemist subjects them to a variety of chemical and instrumental tests to discover what the samples are. Sometimes these samples are extremely small, but sophisticated forensic labs have state-of-the-art equipment capable of identifying the smallest amount of unknown sample.

Another aspect of a forensic chemist’s job is testifying in court. Judges and juries need to be informed about the results of forensic analyses, and it is the forensic chemist’s job to explain those results. Good public-speaking skills, along with a broad background in chemistry, are necessary to be a successful forensic chemist.

## Key Takeaways

• Organic chemistry is the study of the chemistry of carbon compounds.
• Organic molecules can be classified according to the types of elements and bonds in the molecules.

4.7: Organic Chemistry is shared under a CC BY-NC-SA 4.0 license and was authored, remixed, and/or curated by LibreTexts.