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12.S: Organic Chemistry: Alkanes & Halogenated Hydrocarbons (Summary)

To ensure that you understand the material in this chapter, you should review the meanings of the following bold terms in the summary and ask yourself how they relate to the topics in the chapter.

Organic chemistry is the chemistry of carbon compounds, and inorganic chemistry is the chemistry of all the other elements. Carbon atoms can form stable covalent bonds with other carbon atoms and with atoms of other elements, and this property allows the formation the tens of millions of organic compounds. Hydrocarbons contain only hydrogen and carbon atoms.

Hydrocarbons in which each carbon atom is bonded to four other atoms are called alkanes or saturated hydrocarbons. They have the general formula CnH2n + 2. Any given alkane differs from the next one in a series by a CH2 unit. Any family of compounds in which adjacent members differ from each other by a definite factor is called a homologous series.

Carbon atoms in alkanes can form straight chains or branched chains. Two or more compounds having the same molecular formula but different structural formulas are isomers of each other. There are no isomeric forms for the three smallest alkanes; beginning with C4H10, all other alkanes have isomeric forms.

A structural formula shows all the carbon and hydrogen atoms and how they are attached to one another. A condensed structural formula shows the hydrogen atoms right next to the carbon atoms to which they are attached. A line-angle formula is a formula in which carbon atoms are implied at the corners and ends of lines. Each carbon atom is understood to be attached to enough hydrogen atoms to give each carbon atom four bonds.

The IUPAC System of Nomenclature provides rules for naming organic compounds. An alkyl group is a unit formed by removing one hydrogen atom from an alkane.

The physical properties of alkanes reflect the fact that alkane molecules are nonpolar. Alkanes are insoluble in water and less dense than water.

Alkanes are generally unreactive toward laboratory acids, bases, oxidizing agents, and reducing agents. They do burn (undergo combustion reactions).

Alkanes react with halogens by substituting one or more halogen atoms for hydrogen atoms to form halogenated hydrocarbons. An alkyl halide (haloalkane) is a compound resulting from the replacement of a hydrogen atom of an alkane with a halogen atom.

Cycloalkanes are hydrocarbons whose molecules are closed rings rather than straight or branched chains. A cyclic hydrocarbon is a hydrocarbon with a ring of carbon atoms