7.8: Equilibrium Constant
- Page ID
- 51450
Skills to Develop
- Write equilibrium constant expressions
- Use equilibrium constant expressions to solve for unknown concentrations.
- Use known concentrations to solve for the equilibrium constants.
- Explain what the value of \(K\) means in terms of relative concentrations of reactants and products.
In the previous section, you learned about reactions that can reach a state of equilibrium, in which the concentration of reactants and products aren't changing. If these amounts are changing, we should be able to make a relationship between the amount of product and reactant when a reaction reaches equilibrium.
The Equilibrium Constant
Equilibrium reactions are those that do not go to completion but are in a state where the reactants are reacting to yield products and the products are reacting to produce reactants. In a reaction at equilibrium, the equilibrium concentrations of all reactants and products can be measured. The equilibrium constant (\(K\)) is a mathematical relationship that shows how the concentrations of the products vary with the concentration of the reactants. Sometimes, subscripts are added to the equilibrium constant symbol \(K\), such as \(K_\text{eq}\), \(K_\text{c}\), \(K_\text{p}\), \(K_\text{a}\), \(K_\text{b}\), and \(K_\text{sp}\). These are all equilibrium constants and are subscripted to indicate special types of equilibrium reactions.
There are some rules about writing equilibrium constant expressions that you must learn:
- Concentrations of products are multiplied on the top of the expression. Concentrations of reactants are multiplied together on the bottom.
- Coefficients in the equation become exponents in the equilibrium constant expression.
Leave out solids and liquids, as their concentrations do not change in a reaction.
Example 7.8.1
Write the equilibrium constant expression for:
\[\ce{CO} \left( g \right) + 3 \ce{H_2} \left( g \right) \rightleftharpoons \ce{CH_4} \left( g \right) + \ce{H_2O} \left( g \right)\]
Solution:
\[K = \frac{\left[ \ce{CH_4} \right] \left[ \ce{H_2O} \right]}{\left[ \ce{CO} \right] \left[ \ce{H_2} \right]^3}\]
*Note that the coefficients become exponents. Also, note that the concentrations of products in the numerator are multiplied. The same is true of the reactants in the denominator.
Example 7.8.2
Write the equilibrium constant expression for:
\[2 \ce{TiCl_3} \left( s \right) + 2 \ce{HCl} \left( g \right) \rightleftharpoons 2 \ce{TiCl_4} \left( s \right) + \ce{H_2} \left( g \right)\]
Solution:
\[K = \frac{\left[ \ce{H_2} \right]}{\left[ \ce{HCl} \right]^2}\]
*Note that the solids are left out of the expression completely.
Example 7.8.3
Write the equilibrium constant expression for:
\[\ce{P_4} \left( s \right) + 6 \ce{Cl_2} \left( g \right) \rightleftharpoons 4 \ce{PCl_3} \left( s \right)\]
Solution:
\[K = \frac{1}{\left[ \ce{Cl_2} \right]^6}\]
*Note that the only product is a solid, which is left out. That leaves just 1 on top in the numerator.
Example 7.8.4
Write the equilibrium constant expression for:
\[\ce{H_2O} \left( l \right) \rightleftharpoons \ce{H^+} \left( aq \right) + \ce{OH^-} \left( aq \right)\]
Solution:
\[K = \left[ \ce{H^+} \right] \left[ \ce{OH^-} \right]\]
Mathematics with Equilibrium Constant Expressions
The equilibrium constant value is the ratio of the concentrations of the products over the reactants. This means we can use the value of \(K\) to predict whether there are more products or reactants at equilibrium for a given reaction.
If the equilibrium constant is 1 or nearly 1, it indicates that the molarities of the reactants and products are about the same. If the equilibrium constant value was a large number, like 100, or a very large number, like \(1 \times 10^{15}\), it indicates that the products (numerator) are a great deal larger than the reactants. That means that at equilibrium, the great majority of the material is in the form of products and we say the "products are strongly favored". If the equilibrium constant is small, like 0.10, or very small, like \(1 \times 10^{-12}\), it indicates that the reactants are much larger than the products and the reactants are strongly favored. With large \(K\) values, most of the material at equilibrium is in the form of products and with small \(K\) values, most of the material at equilibrium is in the form of the reactants.
The equilibrium constant expression is an equation that we can use to solve for \(K\) or for the concentration of a reactant or product.
Example 7.8.5
For the reaction \(\ce{SO_2} \left( g \right) + \ce{NO_2} \left( g \right) \rightleftharpoons \ce{SO_3} \left( g \right) + \ce{NO} \left( g \right)\), determine the value of \(K\) when the equilibrium concentrations are: \(\left[ \ce{SO_2} \right] = 1.20 \: \text{M}\), \(\left[ \ce{NO_2} \right] = 0.60 \: \text{M}\), \(\left[ \ce{NO} \right] = 1.6 \: \text{M}\), and \(\left[ \ce{SO_3} \right] = 2.2 \: \text{M}\).
Solution:
Step 1: Write the equilibrium constant expression:
\[K = \frac{\left[ \ce{SO_3} \right] \left[ \ce{NO} \right]}{\left[ \ce{SO_2} \right] \left[ \ce{NO_2} \right]}\]
Step 2: Substitute in given values and solve:
\[K = \frac{\left( 2.2 \right) \left( 1.6 \right)}{\left( 1.20 \right) \left( 0.60 \right)} = 4.9\]
Example 7.8.6
Consider the following reaction: \(\ce{CO} \left( g \right) + \ce{H_2O} \left( g \right) \rightleftharpoons \ce{H_2} \left( g \right) + \ce{CO_2} \left( g \right)\); \(K = 1.34\). If the \(\left[ \ce{H_2O} \right] = 0.100 \: \text{M}\), \(\left[ \ce{H_2} \right] = 0.100 \: \text{M}\), and \(\left[ \ce{CO_2} \right] = 0.100 \: \text{M}\) at equilibrium, what is the equilibrium concentration of \(\ce{CO}\)?
Solution:
Step 1: Write the equilibrium constant expression:
\[K = \frac{\left[ \ce{H_2} \right] \left[ \ce{CO_2} \right]}{\left[ \ce{CO} \right] \left[ \ce{H_2O} \right]}\]
Step 2: Substitute in given values and solve:
\[1.34 = \frac{\left( 0.100 \right) \left( 0.100 \right)}{\left[ \ce{CO} \right] \left( 0.100 \right)}\]
Solving for \(\left[ \ce{CO} \right]\), we get: \(\left[ \ce{CO} \right] = 0.0746 \: \text{M}\)
Summary
- The equilibrium constant expression is a mathematical relationship that shows how the concentrations of the products vary with the concentration of the reactants.
- If the value of \(K\) is greater than 1, the products in the reaction are favored; if the value of \(K\) is less than 1, the reactants in the reaction are favored; if \(K\) is equal to 1, neither reactants nor products are favored.
Vocabulary
- Equilibrium constant (\(K\)): A mathematical ratio that shows the concentrations of the products divided by the concentrations of the reactants.
Further Reading/Supplemental Links
- http://en.wikipedia.org/wiki/Chemical_equilibrium
- Crabapples & Equilibrium: http://www.chem.ox.ac.uk/vrchemistry...TML/page05.htm
- Equilibrium Animation/Applet Dots: http://chemconnections.org/Java/equilibrium/