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12.8: Determining the Limiting Reactant

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  • You have ten people that show up for a dinner party. One of the guests brings twenty brownies for dessert. The decision about serving dessert is easy: two brownies are placed on every plate. If someone wants more brownies they will have to wait until they go to the store. There are only enough brownies for everyone to have two.

    Determining the Limiting Reactant

    In the real world, amounts of reactants and products are typically measured by mass or by volume. It is first necessary to convert the given quantities of each reactant to moles in order to identify the limiting reactant.

    Example 12.8.1

    Silver metal reacts with sulfur to form silver sulfide according to the following balanced equation:

    \[2 \ce{Ag} \left( s \right) + \ce{S} \left( s \right) \rightarrow \ce{Ag_2S} \left( s \right)\]

    What is the limiting reactant when \(50.0 \: \text{g} \: \ce{Ag}\) is reacted with \(10.0 \: \text{g} \: \ce{S}\)?

    Solution:

    Step 1: List the known quantities and plan the problem.

    Known

    • Given: \(50.0 \: \text{g} \: \ce{Ag}\)
    • Given: \(10.0 \: \text{g} \: \ce{S}\)

    Unknown

    • Limiting reactant

    Use the atomic masses of \(\ce{Ag}\) and \(\ce{S}\) to determine the number of moles of each present. Then, use the balanced equation to calculate the number of moles of sulfur that would be needed to react with the number of moles of silver present. Compare this result to the actual number of moles of sulfur present.

    Step 2: Solve.

    First, calculate the number of moles of \(\ce{Ag}\) and \(\ce{S}\) present:

    \[50.0 \: \text{g} \: \ce{Ag} \times \frac{1 \: \text{mol} \: \ce{Ag}}{107.87 \: \text{g} \: \ce{Ag}} = 0.464 \: \text{mol} \: \ce{Ag}\]

    \[10.0 \: \text{g} \: \ce{S} \times \frac{1 \: \text{mol} \: \ce{S}}{32.07 \: \text{g} \: \ce{S}} = 0.312 \: \text{mol} \: \ce{S}\]

    Second, find the moles of \(\ce{S}\) that would be required to react with all of the given \(\ce{Ag}\):

    \[0.464 \: \text{mol} \: \ce{Ag} \times \frac{1 \: \text{mol} \: \ce{S}}{2 \: \text{mol} \: \ce{Ag}} = 0.232 \: \text{mol} \: \ce{S} \: \text{(required)}\]

    The amount of \(\ce{S}\) actually present is 0.312 moles. The amount of \(\ce{S}\) that is required to fully react with all of the \(\ce{Ag}\) is 0.232 moles. Since there is more sulfur present than what is required to react, the sulfur is the excess reactant. Therefore, silver is the limiting reactant.

    Step 3: Think about your result.

    The balanced equation indicates that the necessary mole ratio of \(\ce{Ag}\) to \(\ce{S}\) is 2:1. Since there were not twice as many moles of \(\ce{Ag}\) present in the original amounts, that makes silver the limiting reactant.

    There is a very important point to consider about the preceding problem. Even though the mass of silver present in the reaction \(\left( 50.0 \: \text{g} \right)\) was greater than the mass of sulfur \(\left( 10.0 \: \text{g} \right)\), silver was the limiting reactant. This is because chemists must always convert to molar quantities and consider the mole ratio from the balanced chemical equation.

    There is one other thing that we would like to be able to determine in a limiting reactant problem - the quantity of the excess reactant that will be left over after the reaction is complete. We will go back to the sample problem above to answer this question.

    Example 12.8.2

    What is the mass of excess reactant remaining when \(50.0 \: \text{g} \: \ce{Ag}\) reacts with \(10.0 \: \text{g} \: \ce{S}\)?

    \[2 \ce{Ag} \left( s \right) + \ce{S} \left( s \right) \rightarrow \ce{Ag_2S} \left( s \right)\]

    Solution:

    Step 1: List the known quantities and plan the problem.

    Known

    • Excess reactant \(= 0.312 \: \text{mol} \: \ce{S}\) (from Example 12.8.1)
    • Amount of excess reactant needed \(= 0.232 \: \text{mol} \: \ce{S}\) (from Example 12.8.1)

    Unknown

    • Mass of excess reactant remaining after the reaction \(= ? \: \text{g}\)

    Subtract the amount (in moles) of the excess reactant that will react from the amount that is originally is present. Convert moles to grams.

    Step 2: Solve.

    \[0.312 \: \text{mol} \: \ce{S} - 0.232 \: \text{mol} \: \ce{S} = 0.080 \: \text{mol} \: \ce{S} \: \text{(remaining after reaction)}\]

    \[0.080 \: \text{mol} \: \ce{S} \times \frac{32.07 \: \text{g} \: \ce{S}}{1 \: \text{mol} \: \ce{S}} = 2.57 \: \text{g} \: \ce{S}\]

    There are \(2.57 \: \text{g}\) of sulfur remaining when the reaction is complete.

    Step 3: Think about your result.

    There were \(10.0 \: \text{g}\) of sulfur present before the reaction began. If \(2.57 \: \text{g}\) of sulfur remains after the reaction, then \(7.43 \: \text{g} \: \ce{S}\) reacted.

    \[7.43 \: \text{g} \: \ce{S} \times \frac{1 \: \text{mol} \: \ce{S}}{32.07 \: \text{g} \: \ce{S}} = 0.232 \: \text{mol} \: \ce{S}\]

    This is the amount of sulfur that reacted. The problem is internally consistent.

    Summary

    • Determining the limiting reactant requires that all mass quantities first be converted to moles to evaluate the equation.

    Contributors

    • CK-12 Foundation by Sharon Bewick, Richard Parsons, Therese Forsythe, Shonna Robinson, and Jean Dupon.