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15.2: The Formation of Carboxylic Acids

  • Page ID
    16026
    • Anonymous
    • LibreTexts
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    Learning Objectives
    • To describe the preparation of carboxylic acids.

    As we noted previously, the oxidation of aldehydes or primary alcohols forms carboxylic acids:

    primary alcohol.jpg

    In the presence of an oxidizing agent, ethanol is oxidized to acetaldehyde, which is then oxidized to acetic acid.

    ethanol.jpg

    This process also occurs in the liver, where enzymes catalyze the oxidation of ethanol to acetic acid.

    \[\mathrm{CH_3CH_2OH \underset{oxidizing\: agent}{\xrightarrow{alcohol\: dehydrogenase}} CH_3CHO \underset{oxidizing\: agent}{\xrightarrow{alcohol\: dehydrogenase}} CH_3COOH} \nonumber \]

    Acetic acid can be further oxidized to carbon dioxide and water.

    Summary

    Whether in the laboratory or in the body, the oxidation of aldehydes or primary alcohols forms carboxylic acids.


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