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3.3: Unit 3 Practice Problems

  • Page ID
    486033
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    Exercise 1

    Determine all symmetry elements and all unique symmetry operations of the following molecules:

    a) clipboard_e71f7300705f7b7904b5a0b89f18fe779.png

    b) clipboard_efebe6cd6e367d21c8fec0ff81221db25.png

    c) clipboard_ec6d716280ffb6af79d86e00ad667fc4c.png

    d) clipboard_e6e30e5a7bf3d020369c9f6b67437fb94.png

    e) bromine tetrafluoride

    clipboard_e435e2924704b16af2b32201a136fe351.png

    f) Boric acid

    clipboard_e01b0688e37c31938126398654198b8ca.png

    g) Dinitrogen tetroxide

    clipboard_e463967c19a82be7bdfdede0f6b94670e.png

    h) clipboard_ecbb4b6bb7e0eaef2268d0ee0df142410.png

    i) clipboard_e20716edf8e97ac457409c5a6b68cfdbf.png

    j) clipboard_e88ddb4744defc08607e47dbf1cb09ff7.png

    k) clipboard_e719dc28e149072e9850c4033b70912c8.png

    l) clipboard_e3cf3ee5cfbc318500a2be02472b7ca93.png

    m) clipboard_e871960f99e3339d997345c72c463948f.png

    Answer

    a) clipboard_e962a28b06b99d54f7572f2628279fc0e.png

    b) clipboard_e7f7922ff821b7d5844c205f7d3c3cee3.png

    c) clipboard_e4ced8ed1d374a9244f35f22f4f767594.png

    d) clipboard_eb83f73a794a13f92ce18c660ea074c9f.png

    e) clipboard_eca143893b75677595f7d126e641af5a3.png

    f) clipboard_e244cdf8825017217c40e800f7ddc5fee.png

    g) clipboard_ee97073076dd4e89b512d238b008d8b9a.png

    h) clipboard_e05fc76638c04edbd6ee287d17acd7721.png

    i) clipboard_ef7531acc8de39264a5422dfc59208699.png

    j) clipboard_e192b512620da41d498a6599f8d1e268f.png

    k) clipboard_e6ce6f0f27a6da250332dac7bb611f439.png

    l) clipboard_e98e7131475761d8fcfe9d90c98543068.png

    m) clipboard_e808de1f3740e34bea31934a214f5765a.png

    Exercise 2

    When is a molecule chiral?

    a) It has no mirror planes

    b) It is has no inversion center

    c) It has no principal axis

    d) It has no rotation reflections (improper rotations)

    Answer

    d) It has no rotation reflections (improper rotations)

    Exercise 3

    If a molecule has a principal axis Cn , and n additional C2 axes standing perpendicular to Cn then it belongs to

    a) A dihedral point group

    b) A rotational point group

    c) A low symmetry point group

    d) A high symmetry point group

    Answer

    a) A dihedral point group

    Exercise 4

    Which of the following molecules are chiral:

    a) CH4

    b) CHCl3

    c) HCFClBr

    d) HOF

    e) BHFCl

    Answer

    c) HCFClBr

    Exercise 5

    Determine the point groups of the molecules at symmetry.otterbein.edu/challenge/index.html until you feel that you can determine point groups effortlessly


    Dr. Kai Landskron (Lehigh University). If you like this textbook, please consider to make a donation to support the author's research at Lehigh University: Click Here to Donate.


    This page titled 3.3: Unit 3 Practice Problems was last modified on Sat, 18 Jan 2025 05:30:56 GMT and is shared under a CC BY 4.0 license and was authored, remixed, and/or curated by Kai Landskron.

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