Skip to main content
Chemistry LibreTexts

9.1: Acid and Base Strength

  • Page ID
    58832
  • Learning Outcomes

    • Define weak acids and bases.
    • Write an equation representing the behavior of a weak acid.
    • Explain differences between strong and weak acids and strong and weak bases.
    • List the 6 strong acids.
    • Calculate p\(K_\text{a}\) and p\(K_\text{b}\)values.
    • Rank acids in order of strength based on their \(K_\text{a}\) and p\(K_\text{a}\)values.
    • Rank bases in order of strength based on their \(K_\text{b}\) and p\(K_\text{b}\)values.

    So far, we have primarily been defining acids by their ability to donate an \(\ce{H^+}\) ion and bases by their ability to accept an \(\ce{H^+}\) ion. However, acids and bases vary in their relative ability to undergo these processes. Which was mentioned when we talked about weak electrolytes.

    In general, acids can be classified as strong or weak based on the extent to which they produce \(\ce{H_3O^+}\) when dissolved in water. For a generic acid, we can write the following equilibrium reaction:

    \[\ce{HA} \left( aq \right) + \ce{H_2O} \left( l \right) \rightleftharpoons \ce{H_3O^+} \left( aq \right) + \ce{A^-} \left( aq \right)\]

    Using the usual shorthand notation, this equation can also be written as follows:

    \[\ce{HA} \left( aq \right) \rightleftharpoons \ce{H^+} \left( aq \right) + \ce{A^-} \left( aq \right)\]

    This type of equilibrium, in which a proton is being transferred to water, is often indicated by writing the equilibrium constant as \(K_\text{a}\). The relative position of this equilibrium for a given acid determines whether it will be considered strong or weak. When dissolved in water, a strong acid will completely transfer its proton to the solvent. In terms of the equilibrium above, the products will be heavily favored \(\left( K_\text{a} \gg 1 \right)\). In fact, the products are so heavily favored that the reverse reaction is often not even considered, and the proton transfer is written as unidirectional. For example, the strong acid \(\ce{HCl}\) can dissociated in water according to the following reaction:

    \[\ce{HCl} \left( aq \right) + \ce{H_2O} \left( l \right) \rightarrow \ce{H_3O^+} \left( aq \right) + \ce{Cl^-} \left( aq \right)\]

    which is sometimes written as

    \[\ce{HCl} \left( aq \right) \rightarrow \ce{H^+} \left( aq \right) + \ce{Cl^-} \left( aq \right)\]

    to simplify the equation by eliminating the water in the equation because the "\(aq\)" indicates that water is present. At equilibrium, essentially no intact \(\ce{HCl}\) molecules are still present in solution.

    In contrast, the equilibrium for a weak acid favors the reactants. A particularly common type of weak acid is an organic molecule that contains a carboxyl group \(\ce{COOH}\). For example, acetic acid (the acidic component of vinegar) has the formula \(\ce{CH_3COOH}\). Its dissociation equation can be written as follows:

    \[\ce{CH_3COOH} \left( aq \right) + \ce{H_2O} \left( l \right) \rightleftharpoons \ce{H_3O^+} \left( aq \right) + \ce{CH_3COO^-} \left( aq \right)\]

    sometimes written as \(\ce{CH_3COOH} \left( aq \right) \rightleftharpoons \ce{H^+} \left( aq \right) + \ce{CH_3COO^-} \left( aq \right)\). Because we are dealing with a weak acid, \(K_\text{a}\) for this equilibrium is much less than 1. At equilibrium, most of the acetic acid molecules are still intact, and only a small percentage have transferred their protons to the solvent. The \(K_\text{a}\) values for some weak acids are listed in the table below. All weak acids are not equally

    Table \(\PageIndex{1}\)
    Acid Name Structure \(K_\text{a}\)
    hydrofluoric acid \(\ce{H-F}\) \(7.1 \times 10^{-4}\)
    nitrous acid \(\ce{O=N-O-H}\) \(4.5 \times 10^{-4}\)
    formic acid \(\ce{HCOOH}\) \(1.7 \times 10^{-4}\)
    acetic acid \(\ce{CH_3COOH}\) \(1.8 \times 10^{-5}\)
    hydrocyanic acid \(\ce{H-CN}\) \(4.9 \times 10^{-10}\)

    The nature of p\(K_\text{a}\) is also used to indicate the strength of an acid. p\(K_\text{a}\) is determined much like pH by taking the negative logarithm of \(K_\text{a}\). As with pH, it is used to make values easier to manage. As an acid's strength increases, its \(K_\text{a}\) value increases and its p\(K_\text{a}\) value decreases as shown in the table above. Most acids that you will encounter in general chemistry courses are weak acids. There are six common strong acids (see table below). If you recognize these six then you can assume any other acids are weak.

    Acids

    • Hydrochloric acid, \(\ce{HCl}\)
    • Hydrobromic acid, \(\ce{HBr}\)
    • Hydroiodic acid, \(\ce{HI}\)
    • Perchloric acid, \(\ce{HClO_4}\)
    • Nitric acid, \(\ce{HNO_3}\)
    • Sulfuric acid, \(\ce{H_2SO_4}\)

    Strong vs. Weak Bases

    Analogous to the acid dissociation reaction from the previous section, we can write the reaction between a generic base and water as follows:

    \[\ce{B} \left( aq \right) + \ce{H_2O} \left( l \right) \rightleftharpoons \ce{BH^+} \left( aq \right) + \ce{OH^-} \left( aq \right)\]

    The equilibrium constant for a reaction in which a base is deprotonating water (taking water's hydrogen atom) is often given the symbol \(K_\text{b}\). Strong bases and weak bases can then be defined based on the position of this equilibrium. A weak base would have a very small \(K_\text{b}\) value (much less than 1), indicating that most molecules of the base do not remove a proton from water. Conversely, a strong base would have a \(K_\text{b}\) value greater than or equal to 1.

    Nitrogen-containing compounds are a common type of weak base. The lone pair on the nitrogen atom can accept a proton from water as follows:

    \[\ce{NH_3} \left( aq \right) + \ce{H_2O} \left( l \right) \rightleftharpoons \ce{NH_4^+} \left( aq \right) + \ce{OH^-} \left( aq \right)\]

    The equilibrium constant for this reaction is quite low, so most of the \(\ce{NH_3}\) molecules will not remove a proton from water. \(K_\text{b}\) and p\(K_\text{b}\) values for a few weak bases are listed in the table below.

    Table \(\PageIndex{3}\)
    Base \(K_\text{b}\)
    ethylamine \(\left( \ce{CH_3CH_2NH_2} \right)\) \(5.6 \times 10^{-4}\)
    methylamine \(\left( \ce{CH_3NH_2} \right)\) \(4.4 \times 10^{-4}\)
    ammonia \(\left( \ce{NH_3} \right)\) \(1.8 \times 10^{-5}\)

    The only strong bases that are commonly used in general chemistry courses are ionic compounds composed of metal cations and hydroxide anions, such as \(\ce{NaOH}\), \(\ce{KOH}\), or \(\ce{Ba(OH)_2}\).

    Contributors and Attributions

    • CK-12 Foundation by Sharon Bewick, Richard Parsons, Therese Forsythe, Shonna Robinson, and Jean Dupon.

    • Allison Soult, Ph.D. (Department of Chemistry, University of Kentucky)

    • Was this article helpful?