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15.12: Additional Exercises

  • Page ID
    183060
  • General Review

    16-1 Identify which of the following dienes are isolated, conjugated, or cumulated.

    16-2 Identify which pathway gives the thermodynamic or the kinetic product and provide a reason for your answer. 

     

      

    16-3 Draw the resonance structures of the following molecule.

    16-4 Provide the final product of the following reaction.

     

    16-5 Predict the final product for the following reactions.

    16-6 For the following compound, predict which bonds could be broken to give the most probable Diels-Alder dienes that reacted to make the compound. Provide the resulting dienes from the prediction. 

    16-7 Give the final product of the following reaction chain..

    1,2- and 1,4-Addition to Conjugated Dienes

    16-8 Predict all possible products of the following reaction.

    16-9 Identify the kinetic and thermodynamic products of the previous problem, 16-8.

    16-10 Predict the kinetic product(s) of the following reaction and provide proper IUPAC nomenclature.

    Allylic Radicals

    16-11 Draw arrows to show the movement of electrons in the following allylic radical.

    16-12 Show the products of the following reactions.

    16-13 Choose the correct answer of the following reaction.

    SN2 Displacement Reactions of Allylic Halides and Tosylates

    16-14 Predict the products of the following reactions.

    16-15 Choose the correct IUPAC nomenclature of the product of the following reaction and provide its structure.

     

    a)  (3R)-3-ethoxycyclohex-1-ene

    b)  (3S)-3-ethoxycyclohex-1-ene

    c)  ethoxycyclohexane

    d)  cyclohexa-1,3-diene

    16-16 Predict the product of the following reaction.

    Diels-Alder Reactions

    16-17 Predict the products of the following Diels-Alder reactions. 

    16-18 Predict the product of the following reaction.

     

    16-19 Choose the correct answer.