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18.16: Additional Exercises

  • Page ID
    183105
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    General Review

    19-1 Give the product of the following reaction.

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    19-2 For each of the following reactions, give the final product.

    cmG-vpUkrO8S--JXs9MphZhiFO0D0u5TKW1i5QYR2aN8UlOJyLJgsfFXJIFwKzQnbVa5r1anlT0wQm2XoQQ4-RuOZ2f8G5MaElYWgVAvTDCgISwIZ-lR_xHcLZbTSBOVlJIXCbmU

    19-3 For the following reaction, give the final product.

    knNAWhnCVBRK4ss_q2-FcH2BkLB5au-Sr3kPWmU56bim1Yqui1A7vBborHh-XaaiaWLT1PBlWFf8VuZxzdxLvSc2OiyXOwos5HldBN9tuJYVCR1xDyEJ5_6k_qRATLY0LGVg2V2j

    19-4 For the following reactions, identify the side favored at equilibrium.

    9BVK7kKXi8bmg6VBTj31cwafYGV38X4bH4_CR_MAX77CXVn75Gs8WOpDRj8vMgF7TAOjLnmc18TuY6v-wOzaZx6415wbYVkfQR5P189HdtLulvXT9KjLYFLASrfgZxjLaV87V6aA

    19-5 Identify the correct product of the following reaction.

    s8i70bQGnqrcx4wcDbczHYjbJZqtYD3p5yKS7oFgGil0lGJAFUUdj7d2ORX3NKPA6V2qwDmLd4ggmDN9TKnuFkSE0j_9ggFNvtWsHYad8oxFiJ-W5n7CnAKkzrPygQC4CR1aKVXu

    BxNL-4zdEBjIcoYHtTCNiKNHOhNQSjX898Gl1Vk3Adjsjh2NJOFbQuXa3C5i4PSLpYee-P5somWQ8xRTi2Bq0rW0cF25r94OOU7Hf6FIlDMv3oO2_X0wWBk5_J3lKPv5830m2LEj

    19-6 Give the final product of the following chain of reactions.

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    Synthesis of Ketones from Carboxylic Acids

    19-7 Provide the structures of the products of the following reactions.

    CEp00qOaKH26senGf4I-hFWCUyAkbkPMPzgxEcW1P34ey7k_XqexmF4d0lc7saVpQJPXVQJHrSNtBd2PpwhToTzRxweK6csgrBMSRDTiqDgMyq23uZUzDVcERsjD4eXYfqMLZXDn

    19-8 Provide the structure and IUPAC nomenclature of the product of the following reaction.

    RDuVwKOXEAd_bTS9nqpqrXxExaJNCJkikwwGw2x32AN1uB7XEZ_Q8L65r9QIvmzPY2dXTfgjUCb-hbidXzhV0ArOBt2fTk9DVWnZY43Zo_QfgneHJjKgzI2jzRU1g3Ez_ut74yre

    19-9 Choose the correct answer.

    IVZpxbMnGl2Nnwr0OO1a25uFrcasx4ZPvgdoX35f-AUiskX1fi8AEjSzI0Fy0nQ2wDCcAUQGd2sODEDNaqtiA0GXfCrAEt-WO7E9TlcZZrzim1U7e2ZwxbbzeV_KWUUAh5z-XzFh

    WG90hv3hD0cOq2CPEst2AdIjocpBoCxuBvwEAmkLfxurwZmogOQKdoadEAwoqYsliNUYUw60k6MAWZbYwjqie12LRHXjJCpC9PM666b64gTkANA_NAT6QuOVYFu-0J5P7NxZ2e0g

    Synthesis of Ketones and Aldehydes from Acid Chlorides, Esters, and Nitriles

    19-10 Provide the structures of the products of the following reactions.

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    19-11 Choose the correct product of the following reaction.

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    cJ9yJqwsu-egoJEpMDU_AjpiyRzXpInhgfjw6vlZXuIutKeih7fUkyrnwOYCSQ5q4pCgJPc4ErD40yY0xUiuR6wHrzHIs0t0szUus4YNLQC0RyAnloRFjH12MX4NuJZ_BxPNkqLd

    19-12 Choose the correct IUPAC nomenclature of the product of the following reaction.

    KDR2eYm-zvmpl2TjoKATqd-liFr5LZEA4n-7DQdUFMvBjJLrH8QzomYvhFDwM-0xzyjRTouhVkx31lkfkqsyA-ZI_kVufzyieDGBbqDun3bv4oC2rEbo7eXO_Krmk9FHawpMu65L

    a) butanal

    b) 2-methylhexan-3-one

    c) pentan-2-one

    d) 2-methylpentan-2-ol

    Reactions of Ketones and Aldehydes

    19-13 Provide the products of the following reactions.

    u-MTRFb-QGx8668GXlWoYSqnMdctefsjBVV2f6pillincDsF5LfNGDu1_9ghhZdRmORWcFXgjw4r_uEGezWgPXpi9hyyHYa0qreWJpa4Hnpr4S2Of30d4PhPnCyvNs156sqklQoE

    19-14 Suggest a way to make the following compound from butanol. Use any necessary reagents.

    ryiztoUsA1XyN0mj3wQHb-_sQFNPIpcj_YPsCSstvIHaLakwWjwNkIaxJ3fXB_ib4pjTuSMDQA43Mx6i0GxoBZcbLalsulQljWYNEB2Mh3IbQRzUD2FSL1cW7D41X7_3yZ00cHXq

    19-15 Choose the correct product of the following reaction.

    EoHjydgfufGPGPX9TZ8GS1F7zMFEfhsd36V2M6CfwlrVS4zeBEP90jHWl91kICm0Ff9nC0GteEHbGKhKCNMscqwSQYOW9dbFVZiTKGD4z12wFQ-SKLrsfoit9ym0mzGpUTCZJRO6

    a) 2-chloropentane

    b) 1-chlorobutan-1-ol

    c) 2-chlorobutanoic acid

    d) butanoyl chloride

    The Wittig Reaction

    19-16 Predict the structure of the product of the following reaction.

    A3Et-Z7-f8efie5rXibXei5wVALXp3FVe4z-crR-MJqtoCDpor965T0OD0hKfpimDrmi5VUyooxVjI2aa0msfAXllenjylQw1VasqvhHGtSQrgH5Xl8D96HR7zU-ALh9gY31v92Q

    19-17 Provide the product of the following reaction.

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    19-18 Choose the correct product of the following reaction.

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    NApS9wQPrrwYwUeQtsIG9wo4qiLTRomlm2SDKQyemdFvtl1MxBoRq30ATBvdTJAADrLCKiaNvdMbzt51tTFpyPaMA9Iw2ekTsDvGL1vm71GtqaCscKrT55SLLYNyCE52lmUH_l0M

    Formation of Cyanohydrins

    19-19 Predict the structure of the product of the following reaction.

    cuat95rq8Ju5lDjpva9-5ktH7uIPvS68UlPp2t52e-U_ufsZTKRXzLJhOzbP18z8xenOi9QMhrVj2nOCcFya4fWeaBKy3rcJrkeKYjYUsKTBLejZWtvwyl2ymzvm7IFsf66XBZIx

    19-20 Provide the structure of the product of the following reaction.

    6UuMgtPAIo21Sac0D-pamvzthXbjvng83fipVn8IgOo2NgVmidpsAbMoADAwYuGS1C4l98U0BsW2Q6fsk7IV0cAuh-WNrpzS1Afp0CIudWump8NavHlun7gYicRv6RF9eKNLT0Lx

    19-21 Choose the correct IUPAC nomenclature of the product of the following reaction.

    IZNNGxD6301l_ni0fsdGOgEW31Od4fHXSgAPt25I1WhvB2ADiSNa4Xf3WNojwd-kZOQ17fLRRiCn8KG9ohoVNZewIE9hm6sPJ7HTA_XNhJa-shzFJpbfaa7MGeGJMNMSF5vWQa_n

    a) 3-ethylhex-1-yn-3-ol

    b) 2-ethyl-2-hydroxypentanenitrile

    c) 3-(aminomethyl)hexan-3-ol

    d) butanoyl cyanide

    Formation of Imines

    19-22 Predict the product of the following reaction.

    lFsf1yGc5eVMx0tPKbaVX3Ue0SqrcuQ9YKRQjhKhrwQ8lvyqwhaguo_OsdaDIb5yDZSEUJ5rQRZSMB5lHMlVbRozMGa7g6XofYKBR5RpyHVaFN27Ix-u70bgJrxzwckn7Rj7mIMn

    19-23 Provide the structure of the product of the following reaction.

    qX9jiSDH1n79Tn4yE_t1mVPqOkNCmiLrf5Yt3xjRa463SizPVJ5WumFZpE4aSq9Hwnvt6GQiiNj3FWYmdK-6EHAaez9SE9bYa-6cXhwH0-Bf9Q6lRE_AsLIUtKtg1bC-1eBiRoF0

    19-24 Choose the correct IUPAC nomenclature of the product of the following reaction.

    Ztc0AQ4BddoeVzwOCZVvsfwhp2cmwx3fBlx9Qp5sUJuiVQyqE1vuIaTnhnvXl0NBeQSafgiggVo0hw8a2VAhxFwqx_8hsUZm0E_qK9SpfrlPUjikRQvKnDpGZ4leGUnnBPfkwHcT

    a) (4Z)-N-butyloctan-4-imine

    b) (4Z)-N-propyloctan-4-imine

    c) (4Z)-5-propylnon-4-en-1-amine

    d) 4-(butylamino)octan-4-ol

    Condensations with Hydroxylamine and Hydrazines

    19-25 Choose the correct IUPAC nomenclature of the product of the following reaction.

    hTMe-9DV0OV5qcvSdOV7zrUcLCmv0mRqJa5Bwi8DksKesheqBAcf_YXGX2qFossEMxE-C7NurXoZZGCOKNfg8bYSGx6THOW5HcFta5tL9LTFKw126utoFZLtVDcGCmdAZrY6_IY4

    a) 1-ethyl-2-propylhydrazine

    b) N-propoxyethanamine

    c) (1E)-N-ethylbut-1-en-1-amine

    d) (2E)-1-ethyl-2-propylidenehydrazine

    19-26 Provide the structure of the product of the following reaction.

    Qpage9FiMmfXmnIehqJ5YIXczeNWt1aUPZqzoS3Zvn5lFiGElPd0NBF7QXA4uZZ53sjfOObIIqnshLHwtfd0ED8kiX5j2ysHo_OCf32Ha5GLhYdZHuAHHeWUcnBVScjCynCkfggc

    19-27 Provide the structure of the products of the following reactions.

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    Formation and Use of Acetals

    19-28 Provide the structure of the resulting acetal.

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    19-29 Choose the correct structure of the product of the following reaction.

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    2IERo225zeNGcyALUynXeeAQ2rVqrnh-7VhE24LbBeowPZwj3bQYhIc_puua4stH5o3ilFnMbKeO41Uc-xdgGxJ5Wcf0Dvi88WJsygKAJdYH4dWM8Ou1HQFCVBVuyNeY3GDWUwaM

    19-30 Choose the correct IUPAC nomenclature of the product of the following reaction.

    VF3VY30Uoc6vNvjqfaN3ufgqMCn3NikZ59yz3L5eU11aGlKW1lwY-FhuJCB6QtDVPkeyZmUYIDN7Wit6NyxXp9VkWvOWgHvTkRk-74wzvroQoWyz0DPNpYZ4HMwoiWIrgVJJTHPt

    a) (dimethoxymethyl)benzene

    b) benzoic acid

    c) phenylmethanediol

    d) (methoxymethyl)benzene

    Oxidation of Aldehydes and Reductions of Ketones and Aldehydes

    19-31 Draw the structure of the product of the following oxidation reaction.

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    19-32 Draw the structures of the products of the following reduction reactions.

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    19-33 Predict the product of the following reaction and provide its IUPAC nomenclature.

    DU9BhNWZU0EZVMYJEzQYQ8Bkn2VUGSHyLXi98GuOtneelwGTEoCXMGTBO8O_MPy1ZNUYDdPreLTKZGS8NjtetnWWBBJtlBRBPnV_bmNwtWEVS5RCMU-mHwpS2lKTpYASPvNkyKSz


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