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20.14: Solutions to Additional Exercises

  • Page ID
    183134
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    General Review

    22-1

    Possible set of reactants:

    1rL-ab5XpVcjJhHpQ8NCh8G_s56x2u0pLeDeiQbyAXDXtOOIyvQk7jQPtN6KShmdH_ZKo2WiDVkoydFqsydcURnxsCxFOHzqAJyYwCcCihei6aXWZoieh7kvTzZkrsZIk4wBhaFG

    22-2

    jabW9g3v8BBeRo4i3r-J6xDBRHE-LkR0NdzSezI5VhhoWeG1_TJQ0udmPARwuB1RWcNT1myCfFUINnWH-mxA506XVuRvaG3BrDuwsIty5fB15yf3Rf76PgWZWSZY5-MUWwldZ9Pv

    22-3

    n1nUEDns8KC-thXW2ZRd6jnNhDoy-Zv5lDu2xI9H8UATabGxp0aBQXt4a0ZB-hIIXnG7KRy-CsMEuLgp0LhTRNz3JjpEiMJdvtC9Srz4R2CguUTPxbMypO8IbmMpoTXO5Eds82U3

    22-4

    lpDyRlibmNr5UzZdHblsJtv0mKs519PWreNo1ZrXGAfJ-xhAKdQyPPS7JCZutnOoJhpSto31pK4NBWeDNlHvm1ZHV5KAJM53iemrza6Z7cKK6zYvGhIW23Wr-xRoUxcgQ033Ds0_

    Interconversion of Acid Derivatives by Nucleophilic Acyl Substitution

    22-5:

    Z59IINLHEZq8-vgetqmWddV2RxWtuMAj70TrryGn4WFUpp0Dh1JYfERh3XIztALCofCUr4N88mW-aHtNoyRezqQWta573P8jLu11-rVWlo5pZobSu7PkAHOvpv7E2CFEoABQJ5FP

    22-6:

    JLBi-ndESOxu05Mj1hlN-HgR74J6Xg0fd73wf1_YWZU3O_5vV1ycAZLpPD8oXpas7fcAebGiwNlw-BGCth8uPqgzhD8zqF8KalimuqTrtorPz-g78OMM6vH8kdRAOlvhFYfnn0iC

    22-7:

    Answer: B

    Transesterification

    22-8:

    Answer: D

    22-9:

    Under acidic conditions, the carbonyl oxygen atom is protonated, making it a better electrophile for the reaction to occur. Under basic conditions, the alcohol we are trying to add is deprotonated, making it a better nucleophile.

    22-10:

    SQPDadIViuqWrIA7uQYqaceBY5APg0yiZKFLb-4AoIXf-wp7Vn_d_B-Dl03xPfVybs9mgmwp8GnORUf2R1BdTY4plRKcCzLxg7dUtDMRDjVpDaCAocEnV9ng-5dKuF6BAms043Gk

    Hydrolysis of Carboxylic Acid Derivatives

    22-11:

    6bwDyqgyMGNL8MJvBwf-4s3g0kpVgLTewGF8S7LmCnPCDDIS8zA-bnIC0kqH8fvIA8Ofx1lobxzu8OJqcvm8YtfC4YYaI684Ts8-u5bCLWZNwtJBkt47NDQDP_a5DlXEnFeru4So

    22-12:

    fyL9o7ej-8vlN_MezOOSDWl1b635hzQVV7DUHTiNyPEGTUCQwsmBpKGKOrShlOlbectAsVLQUrScZv00IvVv_KQaE1uaq_eX_JCqlTAx4K6OJM8JBZVq408NORkCWp61jYYiiZyr

    22-13:

    oTvLlVZgUTmKTtLKbZ-sVg17LOfyieW56P8a3PfEN5A4MyQ6KJl-gSs7BXldFofxxgl-1_ifnbxZPQkrB4XPKERDx7Xlxgp50vlgBsBBLnVIrfpSvSP6gDsoFd8-B8BuTq30mERo

    Reduction of Acid Derivatives

    22-14:

    _IdZFgrA2Zs0RQgb-6EI0Vyl-UM91IIfFI50ZJr7mBx5r6DGF0fcwfR6QkmGjtoAsI0lRVykJ72OERd8lu3ebMBrIIhlHc5cCzgbKDgzuZ7QNEo8nkvLoGvluFz3V3X8nUcOC2Jr

    22-15:

    zF2AFwLG2GYKLrmfKU8JRmnqRBYu-G05f6Q313v29CMlfRz-av2rTkpPJNVYo91ojgqYZvcejij8Fj4cehKR_Wk_ygmtAHuQlUNAF5s_0de3N-U15nd7zOzGvRar5MT7tTCu55mq

    22-16:

    Answer: C

    Reactions of Acid Derivatives with Organometallic Reagents

    22-17:

    _WcGsvEuMPQdZUCLB6rp1Ilfj5QqxQLlY9qbKuU53c2OWT6aQVB5Zns02GtROJpDUdwIop-2LLBa2FN3BJpy_2639qOvz6OYXqQJJs1dyCucCPF91s5t-wN4IUAh1qi84eG28vNv

    22-18:

    Answer: C

    22-19:

    A possibly better route of synthesis:

    SsDfnBNvIXcHpCifESgBIE6b_P3KAuoe4gABfPRIu76_J5TSg-lSHccQUDg6tjeL2h5p5rbhouz1_zeS_NAIy9luJRc-12sGOBLI39dAYYzig8nhP4eAExFV76HFJHbkrTvR9kR4


    20.14: Solutions to Additional Exercises is shared under a CC BY-NC-SA 4.0 license and was authored, remixed, and/or curated by LibreTexts.

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