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Chemistry LibreTexts

15.13: Solutions to Additional Exercises

  • Page ID
    183061
  • General Review

    16-1

    1. Conjugated
    2. Cumulated
    3. Isolated

    16-2 Pathway A leads to the kinetic product. Since the intermediate formed during this pathway is the most stable intermediate, it forms the fastest and will always give the kinetic product. Pathway B forms the thermodynamic product, which is the most stable final product.

    16-3

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    16-4

    bv8v298FfLyXcLwDvRgCrBPGC96yefB_kWpCGHQ0N1aEXYGNqGAkHg5wzyokYYLNJ_kSyeSd3oA3gsj6Fbw15VcsnS7ID41MPsBJyAAe2vSmr6RrMBZ41HVyKhzYB2hGPInw6YvB

    16-5

    jxOxFQbibrxcDfMPSyuMFjuVz2V1CtoPoH5WjdC98ODtRXUUvP4F8YNIoeCI8Tv29Pjd57TmgjWWoDRw1VvHYs24nUetO7D5ASNZIeK88x6AYOLSgZTx8AUL0TonkUGsI1NMMcUw

    16-6

    NK7p36pZzI7GTjXZrFz0qox6-Ih9DAEyw_qtFSOI78malPd-qTfU-LEHRYKWdhvYEHCVhymDYqQh0fDHOR5Wlbh1yUrqxhq3N12K0Y7bEwcDF-1FErvx3vM-c37V1ZC_lW1_okJA

    16-7

    HwSyOneSTC1t7vZb2XtiKix1FllM3oTmMjcwLumSTyYY9iMdZrmefd0MFPh1_yrQcQGyrnKkk28p1uUItXLDt9xH9ieOC8wIfezj9xiru_tJwDJdUh3V7XLDUzrGsduBj7CqFeBc

    1,2- and 1,4-Addition to Conjugated Dienes

    16-8:

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    16-9:

    _N_oSq9SHlcYBi4hWHKIwv49COztaVlVaUs1XVdyuhPEiTiX_3-R9jLmUiV08jJb5e1iPXO2J43i62KBdOs-g1hwmBv0TDOplbDNpfDGCaUUJ5h_GYCvg6c1MMzGf2wFoK7kx-15

    16-10:

    keDSUhlWG9zI4IbpxDkSAGIi6dlxOtK8ljT_NVawaS4E9cGPRjW7zeHRXSBOhmlNd47OFE-RW8eTcSfqnWuTMAMP5GHX9L9COvLWrmnaIOup3dfoyBQVM93FK2i06j5IaHGiTyxD

    Allylic Radicals

    16-11:

    vCbo74h4PKf7XdE4Wby3vUQhUN-AH7w-OWsgEPNGe0eB_AdnOwlpvS0wvSMSR6y79O263_uw03ildDmjKu6KPH8uBn6Gh_ohEF2Xd_Z2TjfaSkLjU4yKV9VEXpowdbGzsi_txj9A

    16-12:

    crNNbmm8jUxuuBSibNgSX_4gQJFWYn-SR2BgYvW5H6w6Si_WNq_F7zGANEbLhXp8PT2N6MvsFtB3g5tS9ENXGyhbOoOI4ntgVZtAxcHQHgIYS84L9PYPp6q1yLJeJyfoBLMb-rJo

    16-13:

    Answer: C

    SN2 Displacement Reactions of Allylic Halides and Tosylates

    16-14:

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    16-15:

    Answer:

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    16-16:

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    Diels-Alder Reactions

    16-17:

    hl5KPmfxl0FjqY5uue6yKjGeE6JAYukP3nsOHM_zsNbUHBNjhI5tza9G_427sGS9G5PPqEI_ER_r2gceLQCMw6XAv96AKZ44JwPtjOBRrEsPI5_KJAIWasY3dxLiSmHoM_pDNO_C

    16-18:

    gHlPSHmwTBZFedMyjXCcKi4nd55FXb-uwP-B4m-zayIPFE9Lxpgg1xH-ZezD6fraK30BYmOIXsacfWnSnjsm9H7HQCObqocoDEbiidZ6nJUiOhemOt9BXciqtlMR7gP6MZHFnDR3

    16-19:

    Answer: B