13: Radioactivity and Nuclear Chemistry
- Page ID
- 522193
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\(\newcommand{\avec}{\mathbf a}\) \(\newcommand{\bvec}{\mathbf b}\) \(\newcommand{\cvec}{\mathbf c}\) \(\newcommand{\dvec}{\mathbf d}\) \(\newcommand{\dtil}{\widetilde{\mathbf d}}\) \(\newcommand{\evec}{\mathbf e}\) \(\newcommand{\fvec}{\mathbf f}\) \(\newcommand{\nvec}{\mathbf n}\) \(\newcommand{\pvec}{\mathbf p}\) \(\newcommand{\qvec}{\mathbf q}\) \(\newcommand{\svec}{\mathbf s}\) \(\newcommand{\tvec}{\mathbf t}\) \(\newcommand{\uvec}{\mathbf u}\) \(\newcommand{\vvec}{\mathbf v}\) \(\newcommand{\wvec}{\mathbf w}\) \(\newcommand{\xvec}{\mathbf x}\) \(\newcommand{\yvec}{\mathbf y}\) \(\newcommand{\zvec}{\mathbf z}\) \(\newcommand{\rvec}{\mathbf r}\) \(\newcommand{\mvec}{\mathbf m}\) \(\newcommand{\zerovec}{\mathbf 0}\) \(\newcommand{\onevec}{\mathbf 1}\) \(\newcommand{\real}{\mathbb R}\) \(\newcommand{\twovec}[2]{\left[\begin{array}{r}#1 \\ #2 \end{array}\right]}\) \(\newcommand{\ctwovec}[2]{\left[\begin{array}{c}#1 \\ #2 \end{array}\right]}\) \(\newcommand{\threevec}[3]{\left[\begin{array}{r}#1 \\ #2 \\ #3 \end{array}\right]}\) \(\newcommand{\cthreevec}[3]{\left[\begin{array}{c}#1 \\ #2 \\ #3 \end{array}\right]}\) \(\newcommand{\fourvec}[4]{\left[\begin{array}{r}#1 \\ #2 \\ #3 \\ #4 \end{array}\right]}\) \(\newcommand{\cfourvec}[4]{\left[\begin{array}{c}#1 \\ #2 \\ #3 \\ #4 \end{array}\right]}\) \(\newcommand{\fivevec}[5]{\left[\begin{array}{r}#1 \\ #2 \\ #3 \\ #4 \\ #5 \\ \end{array}\right]}\) \(\newcommand{\cfivevec}[5]{\left[\begin{array}{c}#1 \\ #2 \\ #3 \\ #4 \\ #5 \\ \end{array}\right]}\) \(\newcommand{\mattwo}[4]{\left[\begin{array}{rr}#1 \amp #2 \\ #3 \amp #4 \\ \end{array}\right]}\) \(\newcommand{\laspan}[1]{\text{Span}\{#1\}}\) \(\newcommand{\bcal}{\cal B}\) \(\newcommand{\ccal}{\cal C}\) \(\newcommand{\scal}{\cal S}\) \(\newcommand{\wcal}{\cal W}\) \(\newcommand{\ecal}{\cal E}\) \(\newcommand{\coords}[2]{\left\{#1\right\}_{#2}}\) \(\newcommand{\gray}[1]{\color{gray}{#1}}\) \(\newcommand{\lgray}[1]{\color{lightgray}{#1}}\) \(\newcommand{\rank}{\operatorname{rank}}\) \(\newcommand{\row}{\text{Row}}\) \(\newcommand{\col}{\text{Col}}\) \(\renewcommand{\row}{\text{Row}}\) \(\newcommand{\nul}{\text{Nul}}\) \(\newcommand{\var}{\text{Var}}\) \(\newcommand{\corr}{\text{corr}}\) \(\newcommand{\len}[1]{\left|#1\right|}\) \(\newcommand{\bbar}{\overline{\bvec}}\) \(\newcommand{\bhat}{\widehat{\bvec}}\) \(\newcommand{\bperp}{\bvec^\perp}\) \(\newcommand{\xhat}{\widehat{\xvec}}\) \(\newcommand{\vhat}{\widehat{\vvec}}\) \(\newcommand{\uhat}{\widehat{\uvec}}\) \(\newcommand{\what}{\widehat{\wvec}}\) \(\newcommand{\Sighat}{\widehat{\Sigma}}\) \(\newcommand{\lt}{<}\) \(\newcommand{\gt}{>}\) \(\newcommand{\amp}{&}\) \(\definecolor{fillinmathshade}{gray}{0.9}\)In today’s society, the term radioactivity conjures up a variety of images:
- Nuclear power plants producing hydrocarbon-free energy, but with potentially deadly by-products that are difficult to store safely.
- Bombs with the capacity to use nuclear reactions that produce devastating explosions with horrible side effects on the earth as we know it, and on the surviving populations that inhabit it.
- Medical technology that utilizes nuclear chemistry to peer inside living things to detect disease, and the power to irradiate tissues to potentially cure these diseases.
- Fusion reactors that hold the promise of limitless energy with few toxic side products.
Radioactivity has a colorful history and clearly presents a variety of social and scientific dilemmas. In this chapter we will introduce the basic concepts of radioactivity, nuclear equations, and the processes involved in nuclear fission and nuclear fusion. But first we will revisit the inner workings of the atom, as it is important to understand these in order to understand nuclear chemistry
- 13.1: Properties of Atoms
- You learned earlier how all matter in the universe is made out of tiny building blocks called atoms. All modern scientists accept the concept of the atom, but when the concept of the atom was first proposed about 2,500 years ago, ancient philosophers laughed at the idea. It has always been difficult to convince people of the existence of things that are too small to see. We will spend some time considering the evidence (observations) that convince scientists of the existence of atoms.
- 13.2: Isotopes - When the Number of Neutrons Varies
- All atoms of the same element have the same number of protons, but some may have different numbers of neutrons. For example, all carbon atoms have six protons, and most have six neutrons as well. But some carbon atoms have seven or eight neutrons instead of the usual six. Atoms of the same element that differ in their numbers of neutrons are called isotopes. Many isotopes occur naturally.
- 13.3: Atomic Mass - The Average Mass of an Element’s Atoms
- In chemistry, we very rarely deal with only one isotope of an element. We use a mixture of the isotopes of an element in chemical reactions and other aspects of chemistry, because all of the isotopes of an element react in the same manner. That means that we rarely need to worry about the mass of a specific isotope, but instead need to know the average mass of the atoms of an element.
- 13.4: The Discovery of Radioactivity
- Henri Becquerel, Marie Curie, and Pierre Curie shared the discovery of radioactivity.
- 13.5: Types of Radioactivity- Alpha, Beta, and Gamma Decay
- The major types of radioactivity include alpha particles, beta particles, and gamma rays. Fission is a type of radioactivity in which large nuclei spontaneously break apart into smaller nuclei.
- 13.6: Balancing Nuclear Equations
- The major types of radioactivity include alpha particles, beta particles, and gamma rays. Fission is a type of radioactivity in which large nuclei spontaneously break apart into smaller nuclei.
- 13.7: Natural Radioactivity and Half-Life
- During natural radioactive decay, not all atoms of an element are instantaneously changed to atoms of another element. The decay process takes time and there is value in being able to express the rate at which a process occurs. A useful concept is half-life, which is the time required for half of the starting material to change or decay. Half-lives can be calculated from measurements on the change in mass of a nuclide and the time it takes to occur.
- 13.8: Applications of Nuclear Chemistry
- 13.8.1: Detecting Radioactivity
- 13.8.2: Radiocarbon Dating- Using Radioactivity to Measure the Age of Fossils and Other Artifacts
- 13.8.3: The Discovery of Fission and the Atomic Bomb
- 13.8.4: Nuclear Power- Using Fission to Generate Electricity
- 13.8.5: Nuclear Fusion- The Power of the Sun
- 13.8.6: The Effects of Radiation on Life
- 13.8.7: Radioactivity in Medicine
- 13.E: Nuclear Chemistry (Exercises)
- These are exercises and select solutions to accompany Chapter 15 of the "Beginning Chemistry" Textmap formulated around the Ball et al. textbook.
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