Homework 1
- Page ID
- 204071
Name: ______________________________
Section: _____________________________
Student ID#:__________________________
Q1
Write out the complete time-independent Hamiltonians for (each term is explicitly given):
- the helium atom
- the \(H_2^+\) ion
- the \(H_2\) molecule
You may want to refresh yourself on the basics of Chem 110A material:
Q2
What is the Born-Oppenheimer approximation and what do we use it? When would it fail?
Q3
Confirm that the two sp-orbitals are normalized and orthonormal.
Q4
Show that the sp2 hybrid orbital
\[ | sp^2 \rangle = \dfrac{|s \rangle + \sqrt{2}|p \rangle }{\sqrt{3}}\]
is normalized if the \(|s \rangle\) and \(|p_z \rangle\) atomic orbitals are also normalized.
Q5
What is the average energy of a H atom \(|sp^3 \rangle\) hybrid orbital is the energy of the \(|s \rangle\) orbital is \(E_s\) and the energy of the \(|p \rangle\) orbital is \(E_p\)? Hint: this will require solving the variational energy:
\[Energy = \dfrac{\langle sp^2 | \hat{H} | sp^2 \rangle }{ \langle sp^2 | sp^2 \rangle }\]
Q6
When one s and two p atomic orbitals are used to generate hybrid orbitals, how many hybrid orbitals will be generated?