Skip to main content
Chemistry LibreTexts

Blackbody Radiation -- How it works.....

  • Page ID
    74962
  • \( \newcommand{\vecs}[1]{\overset { \scriptstyle \rightharpoonup} {\mathbf{#1}} } \) \( \newcommand{\vecd}[1]{\overset{-\!-\!\rightharpoonup}{\vphantom{a}\smash {#1}}} \)\(\newcommand{\id}{\mathrm{id}}\) \( \newcommand{\Span}{\mathrm{span}}\) \( \newcommand{\kernel}{\mathrm{null}\,}\) \( \newcommand{\range}{\mathrm{range}\,}\) \( \newcommand{\RealPart}{\mathrm{Re}}\) \( \newcommand{\ImaginaryPart}{\mathrm{Im}}\) \( \newcommand{\Argument}{\mathrm{Arg}}\) \( \newcommand{\norm}[1]{\| #1 \|}\) \( \newcommand{\inner}[2]{\langle #1, #2 \rangle}\) \( \newcommand{\Span}{\mathrm{span}}\) \(\newcommand{\id}{\mathrm{id}}\) \( \newcommand{\Span}{\mathrm{span}}\) \( \newcommand{\kernel}{\mathrm{null}\,}\) \( \newcommand{\range}{\mathrm{range}\,}\) \( \newcommand{\RealPart}{\mathrm{Re}}\) \( \newcommand{\ImaginaryPart}{\mathrm{Im}}\) \( \newcommand{\Argument}{\mathrm{Arg}}\) \( \newcommand{\norm}[1]{\| #1 \|}\) \( \newcommand{\inner}[2]{\langle #1, #2 \rangle}\) \( \newcommand{\Span}{\mathrm{span}}\)\(\newcommand{\AA}{\unicode[.8,0]{x212B}}\)

    The definitive reference on blackbody radiation and radiative transfer is by Siegel and Howell. Here's a summary of some of the salient ideas.

    In an enclosure any light radiated by a surface can do only two things: scatter from any object encountered or be absorbed by such an object. Any other phenomenon (taking the energy in a single photon and, perhaps, splitting that into two lower-energy photons) can be thought of as absorption of the original photon, followed by emission of new photons. Thus, eventually, every emitted photon is reabsorbed, and at equilibrium the distribution of photons assumes a steady state known as the Planck distribution. The hemispheric radiance, i.e. the total output at a particular wavelength λ for a black body at a temperature T is:

    \[B_{\lambda,b}(\lambda,T) = \dfrac{2\pi C_1}{\lambda^5\left(e^{\Large\frac{C_2}{\lambda T}} - 1\right)}\]

    with C1 = 0.5944×108 W µm4 m-2 and C2= 14388 µm K. These somewhat strange units indicate that wavelengths are in micrometers, and that the total radiation into a hemisphere (2π steradians) is in units of W m-2 µm-1. A number of practical results follow immediately from this formula:

    1. \[B_{\lambda,b}(\lambda,\Delta\lambda,T) = \dfrac{A}{4\pi (f/\#)^2}\dfrac{2\pi {\Delta\lambda} C_1}{\lambda^5\left(e^{\Large\frac{C_2}{\lambda T}} - 1\right)}\]
    2. Over an arbitrary wavelength range from λ1 to λ2, with source area A and f/number f/#, the flux is

      \[B_{\lambda,b}(\lambda_1,\lambda_2,T) = \dfrac{A}{4\pi (f/\#)^2}
      \int_{\lambda_1}^{\lambda_2}\dfrac{2\pi C_1}{\lambda^5\left(e^{\Large\frac{C_2}{\lambda T}} - 1\right)}d\lambda\]

    3. For real materials at temperature T, the actual intensity is the blackbody intensity times the emissivity. Unfortunately, emissivity is usually symbolized as e, the same symbol used for dielectric constant!
    4. The peak output is at a wavelength such that λmaxT=2897.8 µm K
    5. Total output P=σT4, where σ is the Stefan-Boltzmann constant, 5.67×108 W m-2 K-4. Unlike previous equations this is over an entire sphere, not a hemisphere!

    To play with the effect of temperature on black body radiation, load this spreadsheet. Some questions to think about:

    • For a graphite furnace at 2000 K, what power is radiated? What does this suggest about the size of the furnace and the likelihood that portable apparatus can be built?
    • At room temperature (298 K), where is the peak radiation wavelength? Considering that CO2 has peak absorption at 9.6 and 10.6 µm. What is the connection between these absorption wavelengths and the controversies about global warming?

    Citation:

    R. Siegel and J. R. Howell, Thermal Radiation Heat Transfer, 4th Edition, Taylor and Francis (New York, 2002).


    This page titled Blackbody Radiation -- How it works..... is shared under a CC BY-NC-SA 4.0 license and was authored, remixed, and/or curated by Alexander Scheeline & Thomas M. Spudich via source content that was edited to the style and standards of the LibreTexts platform; a detailed edit history is available upon request.